2-乙基-1,3-丁二烯合成路线 (共 28 条)
反应条件
potassium hydrogensulfate T=190 - 215°C;
参考文献
Marvel; Williams
Journal of the American Chemical Society, 1948 , vol. 70, p. 3843
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Marvel; Myers; Saunders
Journal of the American Chemical Society, 1948 , vol. 70, p. 1698
反应条件
tri-isobutyl aluminium; Ni(mesal)2 in pentane T=25°C; 15 h;
参考文献
Caporusso, Anna Maria; Giacomelly, Giampaolo; Lardicci, Luciano
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1981 , p. 1900 - 1908
反应条件
1: diethyl ether 2: KHSO4 / 190 - 215 °C View Scheme
参考文献
Marvel; Myers; Saunders
Journal of the American Chemical Society, 1948 , vol. 70, p. 1698
反应条件
toluene-4-sulfonic acid
参考文献
Bartlett,P.D. et al.
Journal of the American Chemical Society, 1968 , vol. 90, p. 2049 - 2056
反应条件
manganese(II) 2,4-pentanedionate in pentane T=25°C; 10 h;
参考文献
Caporusso, Anna Maria; Giacomelly, Giampaolo; Lardicci, Luciano
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1981 , p. 1900 - 1908
反应条件
carbon; sodium salt of phosphorous acid T=190 - 200°C;
参考文献
Liwschiz; Korobowa
Doklady Akademii Nauk SSSR, 1958 , vol. 121, p. 474
Doklady Chemistry, 118-123<1958>565
反应条件
tri-isobutyl aluminium in pentane T=25°C; 40 h; Further byproducts given;
参考文献
Caporusso, Anna Maria; Giacomelly, Giampaolo; Lardicci, Luciano
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1981 , p. 1900 - 1908
反应条件
zinc(II) chloride T=0 - 10°C; folgende Pyrolyse bei 100-120grad;
参考文献
Hagemeyer
Industrial and Engineering Chemistry, 1949 , vol. 41, p. 769
反应条件
1,1,1,3,3,3-hexachloro-propan-2-one; triphenylphosphine
参考文献
Magid,R.M. et al.
Journal of Organic Chemistry, 1979 , vol. 44, # 3 p. 359 - 363
反应条件
hydrogen bromide in water Dehydration; Heating; Title compound not separated from byproducts;
参考文献
Viktorov; Zubritskii
Russian Journal of Organic Chemistry, 1999 , vol. 35, # 12 p. 1755 - 1765