1,2,4,5-四苯基苯合成路线 （共 36 条）
反应条件
C42H54Cl2N6Pd; triphenylphosphine; sodium hydroxide in 1,4-dioxane T=105 - 110°C; Suzuki-Miyaura Coupling; 9 h; Inert atmosphere;
参考文献
Shaik, Jeelani Basha; Ramkumar, Venkatachalam; Varghese, Babu; Sankararaman, Sethuraman
Beilstein Journal of Organic Chemistry, 2013 , vol. 9, p. 698 - 704
反应条件
C42H44Cl3N3Pd; caesium carbonate in toluene; tert-butyl alcohol T=80°C; Suzuki coupling; 24 h; Inert atmosphere;
参考文献
Tu, Tao; Sun, Zheming; Fang, Weiwei; Xu, Mizhi; Zhou, Yunfei
Organic Letters, 2012 , vol. 14, # 16 p. 4250 - 4253
反应条件
1-[2-(diphenylphosphino)phenyl]ethanol; bis(acetylacetonate)nickel(II) in diethyl ether T=45°C; 96 h;
参考文献
Yoshikai, Naohiko; Mashima, Hiroko; Nakamura, Eiichi
Journal of the American Chemical Society, 2005 , vol. 127, # 51 p. 17978 - 17979
反应条件
NiF2; methylmagnesium bromide; 1,3-bis(2,6-diisopropylphenyl)imidazolinium chloride in tetrahydrofuran T=0 - 80°C; 27 h; Inert atmosphere;
参考文献
Hatakeyama, Takuji; Hashimoto, Sigma; Ishizuka, Kentaro; Nakamura, Masaharu
Journal of the American Chemical Society, 2009 , vol. 131, # 33 p. 11949 - 11963
反应条件
Woollins’ reagent in toluene 20 h; Heating;
参考文献
Hua, Guoxiong; Li, Yang; Slawin, Alexandra M. Z.; Woollins, J. Derek
Dalton Transactions, 2007 , # 15 p. 1477 - 1480
反应条件
phenyl-magnesium bromide in tetrahydrofuran 16 h; Ambient temperature;
参考文献
Harada, Katsumasa; Hart, Harold; Du, Chi-Jen Frank
Journal of Organic Chemistry, 1985 , vol. 50, # 26 p. 5524 - 5528
反应条件
potassium hydroxide; 1,3-bis(2,4,6-trimethylphenyl)imidazolinium chloride; palladium diacetate in 1,4-dioxane T=95°C; Suzuki coupling;
参考文献
Burukin; Vasil'Ev; Merkulova; Chizhov; Mistryukov; Zlotin
Russian Chemical Bulletin, 2007 , vol. 56, # 7 p. 1467 - 1469
反应条件
dicyclohexyl(2′,6′-dimethoxybiphenyl-2-yl)phosphine; palladium (II) trifluoroacetate; 18-crown-6 ether; potassium carbonate in supercritical carbon dioxide T=110°C; Suzuki-Miyaura reaction; P=82508.3 Torr; 18 h;
参考文献
Kuchurov, Ilya V.; Vasil'Ev, Andrei A.; Zlotin, Sergei G.
Mendeleev Communications, 2010 , vol. 20, # 3 p. 140 - 142
反应条件
1: With 1-[2-(diphenylphosphino)phenyl]ethanol; bis(acetylacetonate)nickel(II) in diethyl ether T=45°C; 96 h; 2: With methanol in diethyl ether Product distribution / selectivity;
参考文献
THE UNIVERSITY OF TOKYO
Patent: WO2006/85628 A1, 2006 ;
Location in patent: Page/Page column 34-35 ;
参考文献
Breslow,R. et al.
Journal of the American Chemical Society, 1965 , vol. 87, # 22 p. 5139 - 5144
