{Et4N}2{Fe4S4(SCH2Ph)4} in N,N-dimethyl-formamide byproducts: S(2-); Electrolysis; electrolysis of a soln. of the cluster compd. during bubbling CO2 through the soln.; addn. of water, filtn., HPLC anal. of the filtrate;
参考文献
Nakazawa, Makoto; Mizobe, Yasushi; Matsumoto, Yoichi; Uchida, Yasuzo; Tezuka, Meguru; Hidai, Masanobu
Bulletin of the Chemical Society of Japan, 1986 , vol. 59, # 3 p. 809 - 814
sodium perchlorate in methanol; water Kinetics; kinetic runs carried out in varying solvent compositions range from 5percent to 30percent (v/v) of methanol, at 293, 300, and 308 K; not isolated;
参考文献
Anbalagan; Geethalakshmi; Poonkodi
Journal of Physical Chemistry A, 2003 , vol. 107, # 12 p. 1918 - 1927
ruthenium (III) chloride in sodium hydroxide Kinetics; byproducts: water; soln. of glycolate, Na2S2O8 and RuCl3 in aq. soln. of NaOH heated between 20 and 70 °C for 25h (8.5 h runs in 3 d); not isolated, S2O8(2-) and C2O4(2-) content determined;
in solid matrix Kinetics; reaction in a KCl-matrix at 97-215°C;; determination by IR;;
参考文献
Hisasune et al.
Journal of Physical Chemistry, 1970 , vol. 74, p. 3225
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Gmelin Handbook: C: MVol.C4, 3.7.4, page 38 - 38
