1,1,2,2,9,9,10,10-八氟[2.2]二聚对二甲苯合成路线 （共 23 条）
反应条件
potassium iodide; zinc in N,N-dimethyl acetamide T=120 - 142°C; 6 h; Catalytic behavior; Reagent/catalystSolventTemperature;
参考文献
LIN, Chun-Hsu; SUN, Chien-Yi; YIN, Yung-Yu; LI, Chun-Shih; CHOU, Yo-Chun
Patent: US2014/11986 A1, 2014 ;
Location in patent: Paragraph 0024 ;
反应条件
TMS-SnBu3; cesium fluoride in tetrahydrofuran; dimethyl sulfoxide T=78°C; 28 h;
参考文献
Dolbier Jr., William R.; Duan, Jian-Xin; Roche, Alex J.
Organic Letters, 2000 , vol. 2, # 13 p. 1867 - 1869
反应条件
copper(I) bromide; palladium dichloride in N,N-dimethyl-formamide T=80°C; Reduction; trifluoromethylation;
参考文献
Journal of Organic Chemistry, , vol. 64, # 25 p. 9137 - 9143
反应条件
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; zinc in N,N-dimethyl-formamide T=25°C; 8 h;
参考文献
Roche; Duan; Dolbier Jr.; Abboud
Journal of Organic Chemistry, 2001 , vol. 66, # 21 p. 7055 - 7058
反应条件
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; zinc in N,N-dimethyl-formamide T=80°C; 8 h;
参考文献
Journal of Organic Chemistry, , vol. 66, # 21 p. 7055 - 7058
反应条件
zinc in N,N-dimethyl acetamide T=100°C; Substitution; 4 h;
参考文献
Organic Letters, , vol. 2, # 13 p. 1867 - 1869
反应条件
1: With sulfuric acid; sodium nitrite in water; acetic acid T=0°C; Diazotization; 2 h; 2: With hydrogen bromide; copper(I) bromide in water; acetic acid T=70°C; Substitution; Sandmeyer reaction; reduction; 1 h;
参考文献
Journal of Organic Chemistry, , vol. 64, # 25 p. 9137 - 9143
反应条件
(1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; copper in N,N-dimethyl-formamide T=80°C; 8 h;
参考文献
Journal of Organic Chemistry, , vol. 66, # 21 p. 7055 - 7058
反应条件
1: With sulfuric acid; sodium nitrite in water; acetic acid T=0°C; Diazotization; 2 h; 2: With hydrogenchloride; copper(l) chloride in water; acetic acid T=70°C; Substitution; Sandmeyer reaction; reduction; 1 h;
参考文献
Journal of Organic Chemistry, , vol. 64, # 25 p. 9137 - 9143
反应条件
tris(dibenzylideneacetone)dipalladium(0) chloroform complex; 3,4-dihydroxy-1-tert-butylbenzene; cesium fluoride in methoxybenzene T=160°C; 24 h;
参考文献
Amii; Hatamoto; Seo; Uneyama
Journal of Organic Chemistry, 2001 , vol. 66, # 21 p. 7216 - 7218
