3-羟基-4-甲基苯乙酮合成路线 （共 14 条）
反应条件
trifluoroacetic acid in dichloromethane T=20°C; 1 h;
参考文献
EP2314570 A1, ;
Page/Page column 49 ;
反应条件
1: With sulfuric acid in water T=20 - 45°C; Inert atmosphere; 2: With sodium nitrite in water T=0°C; Inert atmosphere; 3: in water 5 h; Inert atmosphereReflux;
参考文献
Helvetica Chimica Acta, , vol. 93, # 7 p. 1261 - 1273
反应条件
1: 2.45 g / SnCl2 2: 1) diazotization 2) boiling 20percent H2SO4 View Scheme
参考文献
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, , vol. 23, # 11 p. 1098 - 1102
反应条件
1.1: sodium hydride / Dimethyl imidazolidinone / 1 h / 110 °C 2.1: n-butyllithium / tetrahydrofuran / 0.17 h / -78 °C / Inert atmosphere 2.2: 0.5 h / -78 °C 2.3: -78 °C 3.1: trifluoroacetic acid / dichloromethane / 1 h / 20 °C View Scheme
反应条件
1.1: n-butyllithium / tetrahydrofuran / 0.17 h / -78 °C / Inert atmosphere 1.2: 0.5 h / -78 °C 1.3: -78 °C 2.1: trifluoroacetic acid / dichloromethane / 1 h / 20 °C View Scheme
反应条件
(i) CF3CO2Na, CF3CO2H, MeNO2, (electrochemical oxidation), (ii) aq. NaHCO3; Multistep reaction;
参考文献
Synthesis, , p. 468 - 469
反应条件
1: HNO3 2: (i) (oxidation), (ii) (hydrolysis) View Scheme
参考文献
Australian Journal of Chemistry, , vol. 30, p. 103 - 111
反应条件
sulfuric acid; mercuric sulphate
参考文献
Chemische Berichte, , vol. 92, p. 2141,2148
反应条件
1: liquid NH3; diethyl ether 2: HgSO4; aqueous ethanol.H2SO4 View Scheme
参考文献
Chemische Berichte, , vol. 92, p. 2141,2148
反应条件
(i) (oxidation), (ii) (hydrolysis); Multistep reaction;
参考文献
Australian Journal of Chemistry, , vol. 30, p. 103 - 111
