双(三环己基磷)钯(0)合成路线 （共 19 条）
反应条件
in toluene (Ar or N2, Schlenk) to a toluene-soln. of complex was added twice the molar amount of phosphine, the mixt. was stirred for 1 h at room temp.; the solvent was removed under reduced pressure, the solid was washed twice with hexane, dried in vac.;
参考文献
Tanabe, Makoto; Ishikawa, Naoko; Osakada, Kohtaro
Organometallics, 2006 , vol. 25, # 3 p. 796 - 798
反应条件
tricyclohexylphosphine in acetone (N2 or Ar); added a soln. of P-compound to a soln. of Pd-complex; evapd. after 15 min; added n-hexane; filtered; cooled for 2 h at -78°C; pptd.; filtered; dried in vacuo;
参考文献
Organometallics, , vol. 10, p. 1038 - 1044
反应条件
in methanol byproducts: B(C6H5)3, benzene; (N2 or Ar); soln. of B-compound dropped into soln. of Pd-complex; pptd. after 0.5 h; allowed to stand for 2 h at room temp. and for 2 h at -78°C; filtered; dried in vacuo; IR, NMR;
参考文献
Leoni, Piero; Sommovigo, Milena; Pasquali, Marco; Midollini, Stefano; Braga, Dario; Sabatino, Piera
Organometallics, 1991 , vol. 10, p. 1038 - 1044
反应条件
sodium t-butanolate in further solvent(s) react. of Fe and Pd complexes (molar ratio 1.1:1) and PhBr in the presence of NaO-t-Bu; treated with PCy3; not isolated; detd. by (1)H and (31)P NMR spectra;
参考文献
Journal of the American Chemical Society, , vol. 122, # 43 p. 10718 - 10719
反应条件
in tetrahydrofuran; THF-d8 (tetrahydrofuran-d8) T=100°C; P=760.051 Torr; 16 h; Inert atmosphere;
参考文献
European Journal of Organic Chemistry, , # 3 p. 443 - 447
反应条件
1: neat (no solvent) 2: benzene View Scheme
参考文献
Journal of the American Chemical Society, , vol. 126, # 4 p. 1184 - 1194
反应条件
4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl-4',4',5',5'-tetramethyl-1,3,2-dioxaborolane in toluene T=70°C; 0.166667 h; Inert atmosphere; Reagent/catalystConcentrationTimeSolvent;
参考文献
Wei, Carolyn S.; Davies, Geraint H. M.; Soltani, Omid; Albrecht, Jacob; Gao, Qi; Pathirana, Charles; Hsiao, Yi; Tummala, Srinivas; Eastgate, Martin D.
Angewandte Chemie - International Edition, 2013 , vol. 52, # 22 p. 5822 - 5826
Angew. Chem., 2013 , vol. 52, # 22 p. 5822 - 5826,5
反应条件
in benzene addn. of 1 equiv. of tricyclohexylphosphine to ((1-adamantyl)P(t-Bu)2)PdBr(Ph) in benzene;
参考文献
Stambuli, James P.; Incarvito, Christopher D.; Buehl, Michael; Hartwig, John F.
Journal of the American Chemical Society, 2004 , vol. 126, # 4 p. 1184 - 1194
反应条件
in benzene-d6 byproducts: Pd; complex reacted slowly with excess of H2 under atm. pressure in C6D6;
参考文献
Watanabe, Chieko; Iwamoto, Takeaki; Kabuto, Chizuko; Kira, Mitsuo
Chemistry Letters, 2007 , vol. 36, # 2 p. 284 - 285
反应条件
1: tetrahydrofuran; benzene 2: H2O / benzene-d6 View Scheme
参考文献
Inorganic Chemistry, , vol. 30, p. 3371 - 3381
