醋酸(E)-11-十四烯酯合成路线 （共 62 条）
反应条件
pyridine in dichloromethane T=20°C; 12 h; Overall yield = 84 percent; Overall yield = 0.19 g;
参考文献
GRUBBS, ROBERT H.; HERBERT, MYLES B.; WICKENS, ZACHARY K.; MARX, VANESSA M.
Patent: US2013/231499 A1, 2013 ;
Location in patent: Paragraph 0191; 0192 ;
反应条件
pyridine in diethyl ether
参考文献
Rossi, Renzo; Carpita, Adriano; Gaudenzi, Loretta; Quirici, Maria Grazia
Gazzetta Chimica Italiana, 1980 , vol. 110, # 4 p. 237 - 246
反应条件
in acetic acid T=80°C; Yield given. Title compound not separated from byproducts;
参考文献
3M Innovative Properties Company
Patent: US6838576 B1, 2005 ;
Location in patent: Page column 11-12 ;
反应条件
potassium iodide in acetic acid 20 h; Heating;
参考文献
Zakharkin, L. I.; Petrushkina, E. A.
Journal of Organic Chemistry USSR (English Translation), 1982 , vol. 18, # 8 p. 1419 - 1422
Zhurnal Organicheskoi Khimii, 1982 , vol. 18, # 8 p. 1623 - 1628
反应条件
in pyridine; acetic acid T=0°C; 13 h;
参考文献
Vig; Kad; Sabharwal; Dogra; Sharma
Journal of the Indian Chemical Society, 1989 , vol. 66, # 4 p. 233 - 235
反应条件
1: 1.) activated Mg; 2.) Li2CuCl4 / 1.)THF, N2 2.) THF, -10 deg C, 5.5 h 2: 92 percent / acetic acid; pyridine / 13 h / 0 °C View Scheme
参考文献
Moiseenkov, Alexander M.; Czeskis, Boris A.; Ivanova, Natalya M.; Nefedov, Oleg M.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1991 , p. 2639 - 2649
参考文献
TillieChem, Inc.
Patent: US6696597 B2, 2004 ;
反应条件
1: PBr3 / 1.) pyridine, hexane, 3-5 deg C, 3h; 2.) 20 deg C, 12 h 2: 1.) Mg / 2.) Li2CuCl4 / 1.) THF; 2.) 0 deg C, 3 h, 20 deg C, 2 h 3: 88 percent / potassium iodide / acetic acid / 20 h / Heating View Scheme
参考文献
Odinokov, V. N.; Ishmuratov, G. Yu.; Galeeva, R. I.; Kharisov, R. Ya.; Sokol'skaya, O. V.; at al.
Journal of Organic Chemistry USSR (English Translation), 1988 , vol. 24, # 4 p. 646 - 651
Zhurnal Organicheskoi Khimii, 1988 , vol. 24, # 4 p. 719 - 724
反应条件
1: 1.) 0.75M 9-borabicyclo<3.3.1>nonane; 2.) 3N NaOH, 26percent H2O2 / 1.) THF, 0 deg C, 2-3 h; 2.) 20 deg C, 2-3 h 2: PBr3 / 1.) pyridine, hexane, 3-5 deg C, 3h; 2.) 20 deg C, 12 h 3: 1.) Mg / 2.) Li2CuCl4 / 1.) THF; 2.) 0 deg C, 3 h, 20 deg C, 2 h 4: 88 percent / potassium iodide / acetic acid / 20 h / Heating View Scheme
参考文献
Zakharkin, L. I.; Petrushkina, E. A.
Journal of Organic Chemistry USSR (English Translation), 1982 , vol. 18, # 8 p. 1419 - 1422
Zhurnal Organicheskoi Khimii, 1982 , vol. 18, # 8 p. 1623 - 1628
反应条件
1: 1.) Mg / 2.) Li2CuCl4 / 1.) THF; 2.) 0 deg C, 3 h, 20 deg C, 2 h 2: 88 percent / potassium iodide / acetic acid / 20 h / Heating View Scheme
参考文献
Zakharkin, L. I.; Petrushkina, E. A.
Journal of Organic Chemistry USSR (English Translation), 1982 , vol. 18, # 8 p. 1419 - 1422
Zhurnal Organicheskoi Khimii, 1982 , vol. 18, # 8 p. 1623 - 1628
