环戊二烯基双(三苯基膦)氯化钌(II)合成路线 （共 32 条）
反应条件
tetrabutyl-ammonium chloride; tetra-n-butylammonium tetrafluoroborate in dichloromethane Electrochem. Process; controlled potential electrolysis at 0.60V, CH2Cl2, 0.05 M Bu4NBF4/0.02M Bu4NCl, 6-10 h; evapd., extd. with petroleum ether, then ethyl ether, evapn., detected by NMR-spectra;
参考文献
Organometallics, , vol. 3, p. 1749 - 1754
反应条件
tetrabutyl-ammonium chloride; tetra-n-butylammonium tetrafluoroborate in dichloromethane Electrochem. Process; controlled potential electrolysis at 0.60V, CH2Cl2, 0.05 M Bu4BF4/0.02 M Bu4NCl, 6-10 h; evapn., extn. (petroleum ether, then ethyl ether), evapn., detection byNMR-spectrum;
参考文献
Organometallics, , vol. 3, p. 1749 - 1754
反应条件
in methyl ethyl ketone=butan-2-one stirred (12 h); refluxed (16 h);
参考文献
Journal of Organometallic Chemistry, , vol. 312, p. C64 - C66
反应条件
in dichloromethane-d2 byproducts: (C2H4S)n; PPh4Cl added to CD2Cl2-soln. of Ru-thiiran complex at 0°C; decompn. by warming to room temp.;
参考文献
Journal of the American Chemical Society, , vol. 110, p. 2332 - 2334
反应条件
in ethanol; water triphenylphosphine added to RuCl3*aq, reflux, 5 min, cyclopentadiene added to soln., reflux, 1 h; washed with ethanol, recrystn. from CH2Cl2/n-hexane, elem. anal.;
参考文献
Journal of Organometallic Chemistry, , vol. 215, # 1 p. 87 - 96
反应条件
in chloroform-d1 N2, stirred at room temp. for ca. 4 h with aq. HCl; solvent removed (vac.), washed (diethyl ether);
参考文献
European Journal of Inorganic Chemistry, , # 3 p. 649 - 655
反应条件
in chloroform-d1 N2, stirred at room temp. for ca. 4 h with aq. HCl; solvent removed (vac.), washed (diethyl ether);
参考文献
European Journal of Inorganic Chemistry, , # 3 p. 649 - 655
反应条件
hydrogenchloride in methanol Ru-complex and sulfonic acid stirred (25°C, 20 min), addn. of aqueous HCl, left standing (4 d); crystn.;
参考文献
Journal of Organometallic Chemistry, , vol. 361, p. 219 - 230
反应条件
in benzene-d6 a soln. in C6D6 was treated with twofold molar amount of PPh3 at 50°C (Ar);
参考文献
Journal of Organometallic Chemistry, , vol. 617, # 1 p. 511 - 519
反应条件
in decane byproducts: 1-butene; at 100°C under nitrogen for 5min.;
参考文献
Journal of Organometallic Chemistry, , vol. 291, p. C20 - C22
