反应条件
hydrogen in dichloromethane dry solvents; degassing isonitrile and Mo-compd. dissolved in CH2Cl2, placing under hydrogen (375-400 Torr), stirring and warming to 70°C (3 days), crystn.; removal of solvent (reduced pressure), extn. (toluene), filtration, shaking residue (Et2O/Na2CO3), filtration, extn. residue (MeCN), filtration, crystn. by addn. of Et2O, filtration, drying in vac.; (CpMo)2(S2CH2)2 not isolated, detn. by (1)H-NMR spektr;
参考文献
Organometallics, , vol. 9, p. 1607 - 1617
