三(三苯基膦)(三氟甲基)铜(I)合成路线 （共 24 条）
反应条件
1: trifluoromethane acid With potassium tert-butylate; copper(l) chloride in N,N-dimethyl-formamide T=20°C; Inert atmosphere; 2: triphenylphosphine in N,N-dimethyl-formamide Inert atmosphere;
参考文献
FUNDACIO PRIVADA INSTITUT CATALA D'INVESTIGACIO QUIMICA (ICIQ); GRUSHIN, Vladimir; ZANARDI, Alessandro
Patent: WO2012/113726 A1, 2012 ;
Location in patent: Page/Page column 57 ;
反应条件
in tetrahydrofuran byproducts: Me3SiOCH(CF3)2; (N2 or Ar); stirred at 50°C for 12 h; evapd. (vac.), washed (cold hexane), dried (vac.), recrystd. (THF); elem. anal.;
参考文献
Usui, Yoko; Noma, Junko; Hirano, Masafumi; Komiya, Sanshiro
Inorganica Chimica Acta, 2000 , vol. 309, # 1-2 p. 151 - 154
反应条件
in methanol mixt. of CuF2*3H2O and PPh3 in MeOH stirred under reflux in air overnight, filtration, filtrate evapd. to dryness under vac., residue dried under vac. overnight, treated with THF and CF3SiMe3 in glove box, mixt. stirred under Ar for 2 h; solid quickly filtered off in air, washed successively with dry THF and hexane, dried under vac.;
参考文献
Tomashenko, Olesya A.; Escudero-Adan, Eduardo C.; Martinez Belmonte, Marta; Grushin, Vladimir V.
Angewandte Chemie - International Edition, 2011 , vol. 50, # 33 p. 7655 - 7659
反应条件
in tetrahydrofuran byproducts: Me3SiOPh; (N2 or Ar); at 50°C for 12 h; elem. anal.;
参考文献
Usui, Yoko; Noma, Junko; Hirano, Masafumi; Komiya, Sanshiro
Inorganica Chimica Acta, 2000 , vol. 309, # 1-2 p. 151 - 154
反应条件
4,4'-di-tert-butyl-2,2'-dipyridyl in toluene T=80°C;
参考文献
Tomashenko, Olesya A.; Escudero-Adan, Eduardo C.; Martinez Belmonte, Marta; Grushin, Vladimir V.
Angewandte Chemie - International Edition, 2011 , vol. 50, # 33 p. 7655 - 7659
反应条件
4,4'-di-tert-butyl-2,2'-dipyridyl in toluene T=80°C; 22 h;
参考文献
Tomashenko, Olesya A.; Escudero-Adan, Eduardo C.; Martinez Belmonte, Marta; Grushin, Vladimir V.
Angewandte Chemie - International Edition, 2011 , vol. 50, # 33 p. 7655 - 7659
反应条件
4,4'-di-tert-butyl-2,2'-dipyridyl in toluene T=80°C;
参考文献
Tomashenko, Olesya A.; Escudero-Adan, Eduardo C.; Martinez Belmonte, Marta; Grushin, Vladimir V.
Angewandte Chemie - International Edition, 2011 , vol. 50, # 33 p. 7655 - 7659
反应条件
4,4'-di-tert-butyl-2,2'-dipyridyl in toluene T=80°C;
参考文献
Tomashenko, Olesya A.; Escudero-Adan, Eduardo C.; Martinez Belmonte, Marta; Grushin, Vladimir V.
Angewandte Chemie - International Edition, 2011 , vol. 50, # 33 p. 7655 - 7659
反应条件
4,4'-di-tert-butyl-2,2'-dipyridyl in toluene T=80°C;
参考文献
Tomashenko, Olesya A.; Escudero-Adan, Eduardo C.; Martinez Belmonte, Marta; Grushin, Vladimir V.
Angewandte Chemie - International Edition, 2011 , vol. 50, # 33 p. 7655 - 7659
反应条件
4,4'-di-tert-butyl-2,2'-dipyridyl
参考文献
Tomashenko, Olesya A.; Escudero-Adan, Eduardo C.; Martinez Belmonte, Marta; Grushin, Vladimir V.
Angewandte Chemie - International Edition, 2011 , vol. 50, # 33 p. 7655 - 7659
