2,2,5,5-四甲基-1-吡咯烷基氧基合成路线 （共 7 条）
反应条件
sodium tungstate; dihydrogen peroxide in methanol; water 0 deg C (adding), then 25 deg C, 24 h;
参考文献
Couet, W. R.; Brasch, R. C.; Sosnovsky, G.; Lukszo, J.; Prakash, I.; et. al.
Tetrahedron, 1985 , vol. 41, # 7 p. 1165 - 1172
反应条件
1: 73 percent / hydrazine hydrate, KOH / 14 h / 135 °C / in diethylene glycol monoethyl ether 2: 54 percent / 30percent H2O2, Na2WO4 / methanol; H2O / 0 deg C (adding), then 25 deg C, 24 h View Scheme
参考文献
Couet, W. R.; Brasch, R. C.; Sosnovsky, G.; Lukszo, J.; Prakash, I.; et. al.
Tetrahedron, 1985 , vol. 41, # 7 p. 1165 - 1172
反应条件
1: Br2 / acetic acid 2: NH4OAc 3: NaOBr / H2O 4: 73 percent / hydrazine hydrate, KOH / 14 h / 135 °C / in diethylene glycol monoethyl ether 5: 54 percent / 30percent H2O2, Na2WO4 / methanol; H2O / 0 deg C (adding), then 25 deg C, 24 h View Scheme
参考文献
Couet, W. R.; Brasch, R. C.; Sosnovsky, G.; Lukszo, J.; Prakash, I.; et. al.
Tetrahedron, 1985 , vol. 41, # 7 p. 1165 - 1172
反应条件
1: NaOBr / H2O 2: 73 percent / hydrazine hydrate, KOH / 14 h / 135 °C / in diethylene glycol monoethyl ether 3: 54 percent / 30percent H2O2, Na2WO4 / methanol; H2O / 0 deg C (adding), then 25 deg C, 24 h View Scheme
参考文献
Couet, W. R.; Brasch, R. C.; Sosnovsky, G.; Lukszo, J.; Prakash, I.; et. al.
Tetrahedron, 1985 , vol. 41, # 7 p. 1165 - 1172
反应条件
1: NH4OAc 2: NaOBr / H2O 3: 73 percent / hydrazine hydrate, KOH / 14 h / 135 °C / in diethylene glycol monoethyl ether 4: 54 percent / 30percent H2O2, Na2WO4 / methanol; H2O / 0 deg C (adding), then 25 deg C, 24 h View Scheme
参考文献
Couet, W. R.; Brasch, R. C.; Sosnovsky, G.; Lukszo, J.; Prakash, I.; et. al.
Tetrahedron, 1985 , vol. 41, # 7 p. 1165 - 1172
参考文献
Scott, Alan C.; Tedder, John M.; Walton, John C.; Mhatre, Sushila
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1980 , p. 260 - 266
反应条件
1: Zn dust 3: <Ox(1-)> View Scheme
参考文献
Scott, Alan C.; Tedder, John M.; Walton, John C.; Mhatre, Sushila
Journal of the Chemical Society, Perkin Transactions 2: Physical Organic Chemistry (1972-1999), 1980 , p. 260 - 266
