5-溴-2,4-二甲氧基苯甲酸合成路线 （共 26 条）
反应条件
[VO((R,R)-N,N-disalicylidenecyclohexane-1,2-diamine-2H)(methanol)]ClO4; dihydrogen peroxide; potassium bromide in acetonitrile T=60 - 80°C; 12 h; High-pressure reactor;
参考文献
Si, Tapan Kumar; Drew, Michael G.B.; Mukherjea, Kalyan Kumar
Polyhedron, 2011 , vol. 30, # 13 p. 2286 - 2293
反应条件
1: 4-6-dibromoresorcinal dimethyl ether With n-butyllithium in tetrahydrofuran T=-78°C; Inert atmosphere; 2: carbon dioxide in tetrahydrofuran T=-78°C; 0.75 h; Further stages;
参考文献
Pahari, Pallab; Rohr, Juergen
Journal of Organic Chemistry, 2009 , vol. 74, # 7 p. 2750 - 2754
反应条件
caesium carbonate in N,N-dimethyl-formamide 16 h; Heating / reflux;
参考文献
WO2006/87077 A2, ;
Page/Page column 68 ;
反应条件
sodium hydroxide T=60 - 70°C;
参考文献
Journal of the American Chemical Society, , vol. 48, p. 3127
反应条件
2: bromine View Scheme
参考文献
Itsuu Kenkyusho Nempo, , # 6 p. 4,7; engl. Ref. S. 34, 37
Chem.Abstr., , p. 10112
反应条件
permanganate(VII) ion
参考文献
Journal of the Chemical Society, , p. 1580
参考文献
Sci. Rep. Saitama Univ., , vol. <A> 2, p. 111,114
参考文献
Sci. Rep. Saitama Univ., , vol. <A> 2, p. 111,114
反应条件
potassium permanganate; hydroxide
参考文献
Journal of the Indian Chemical Society, , vol. 48, # 3 p. 209 - 216
反应条件
1: formic acid; sodium acetate; bromine 2: Methylierung 3: permanganate View Scheme
参考文献
Journal of the Chemical Society, , p. 1580
