9,10-亚甲基油酸甲酯合成路线 （共 11 条）
反应条件
n-butyllithium T=-80°C;
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , # 14 p. 1547 - 1548
反应条件
1: 1) BuLi, 2) HMPA / 1) Et2O, -40 to 20 deg C, 30 min, 2) -40 deg C 2: 79 percent / I2 / diethyl ether 3: deprotection 4: aq. KMnO4 / Bu4NBr / benzene 5: diethyl ether 6: 76 percent / BuLi / -80 °C View Scheme
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , # 14 p. 1547 - 1548
反应条件
1: 1) BuLi, 2) HMPA / 1) Et2O, -40 to 20 deg C, 30 min, 2) -40 deg C 2: 79 percent / I2 / diethyl ether 3: deprotection 4: aq. KMnO4 / Bu4NBr / benzene 5: diethyl ether 6: 76 percent / BuLi / -80 °C View Scheme
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , # 14 p. 1547 - 1548
反应条件
1: 79 percent / I2 / diethyl ether 2: deprotection 3: aq. KMnO4 / Bu4NBr / benzene 4: diethyl ether 5: 76 percent / BuLi / -80 °C View Scheme
参考文献
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), , # 14 p. 1547 - 1548
反应条件
1: butyl lithium, HMPA / Ambient temperature 2: aq. NaOH 3: aq. Bu4N(1+)OH(1-) / CH2Cl2 View Scheme
参考文献
Tetrahedron Letters, , vol. 33, # 11 p. 1521 - 1522
反应条件
1: aq. NaOH 2: aq. Bu4N(1+)OH(1-) / CH2Cl2 View Scheme
参考文献
Tetrahedron Letters, , vol. 33, # 11 p. 1521 - 1522
反应条件
tetra(n-butyl)ammonium hydroxide in dichloromethane
参考文献
Tetrahedron Letters, , vol. 33, # 11 p. 1521 - 1522
参考文献
Journal of the Indian Chemical Society, , vol. 33, p. 111,112
反应条件
1: (i) Br2, (ii) KOH, ethane-1,2-diol, (iii) /BRN= 1098229/, H2SO4 2: (i) Cu, (ii) /BRN= 107654/ 3: (i) aq. KOH, nPrOH, (ii) HClO4, Ac2O, (iii) NaBH4, DMSO, (iv) /BRN= 102415/ View Scheme
参考文献
Journal of Organic Chemistry, , vol. 37, p. 3245 - 3248
反应条件
1: (i) Cu, (ii) /BRN= 107654/ 2: (i) aq. KOH, nPrOH, (ii) HClO4, Ac2O, (iii) NaBH4, DMSO, (iv) /BRN= 102415/ View Scheme
参考文献
Journal of Organic Chemistry, , vol. 37, p. 3245 - 3248
