5-溴-2-羟基环庚烷-2,4,6-三烯-1-酮合成路线 （共 14 条）
反应条件
dimethyl sulfoxide; trifluoroacetic anhydride in dichloromethane T=-60°C; 1.5 h;
参考文献
Amon, Catherine M.; Banwell, Martin G.; Gravatt, G.Lance
Journal of Organic Chemistry, 1987 , vol. 52, # 22 p. 4851 - 4855
反应条件
1: With dimethyl sulfoxide; trifluoroacetic anhydride in dichloromethane T=-60°C; 1.5 h; 2: With triethylamine in dichloromethane T=-60 - 0°C; 2 h; Further stages.;
参考文献
Deveau, Amy Morin; Macdonald, Timothy L.
Tetrahedron Letters, 2004 , vol. 45, # 4 p. 803 - 807
参考文献
Brasen,W.R. et al.
Journal of the American Chemical Society, 1961 , vol. 83, p. 3125 - 3135
反应条件
1: Br2 / Irradiation 2: aq. KOH View Scheme
参考文献
Brasen,W.R. et al.
Journal of the American Chemical Society, 1961 , vol. 83, p. 3125 - 3135
反应条件
in decalin T=190°C; 10 h;
参考文献
Takeshita, Hitoshi; Mametsuka, Hiroaki; Chisaka, Atsuko; Matsuo, Norihide
Chemistry Letters, 1981 , p. 73 - 76
反应条件
dimethyl sulfoxide; triethylamine; trifluoroacetic anhydride 1.) -60 deg C, 1.5 h, 2.) -60 deg C, 1.5 h; Yield given. Multistep reaction;
参考文献
Banwell, Martin G.; Onrust, Rene
Tetrahedron Letters, 1985 , vol. 26, # 37 p. 4543 - 4546
反应条件
bromine; acetic acid
参考文献
Cook et al.
Journal of the Chemical Society, 1951 , p. 2244,2247
Full Text Show Details
Nozoe et al.
Proceedings of the Japan Academy, 1950 , vol. 26, # 7 p. 38,42
Proceedings of the Japan Academy, 1951 , vol. 27, p. 18,21
反应条件
sulfuric acid; water; hydrogen bromide; hydroxylamine; copper(l) chloride
参考文献
Nozoe et al.
Sci. Rep. Tohoku Univ., Ser. 1: Phys., Chem., Astron., 1953 , vol. # 37, p. 419,388,397
反应条件
Yield given. Multistep reaction;
参考文献
Menard, D.; St-Jacques M.; Bagli, J. F.
Canadian Journal of Chemistry, 1982 , vol. 60, p. 231 - 238
反应条件
triethylamine; tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran T=100°C; 20 h;
参考文献
Horino, Hiroshi; Asao, Toyonobu; Inoue, Naoto
Bulletin of the Chemical Society of Japan, 1991 , vol. 64, # 1 p. 183 - 190
