in neat (no solvent) heating under reflux (4 h), cooling; filtration of polymeric HNCS, further flash chromy. (SiO2, CH2Cl2 (30-40percent) in light petroleum);
参考文献
Dunn, Peter J.; Morris, Janet L.; Rees, Charles W.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1988 , p. 1745 - 1748
Dixon; Taylor
Journal of the Chemical Society, 1913 , vol. 103, p. 974 - 974
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Gmelin Handbook: C: MVol.D3, 6.2.5.6.7.12, page 239 - 239
in neat (no solvent) byproducts: AgBr; freshly prepared AgSCN was packed with a glass wool in a U-tube, dried in vacuo at 100°C for several hs., cooled to room temp., Br2 vapour was passed over the solid; not isolated, identified by microwave spectrum;
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Jemson, H. M.; Lewis-Bevan, W.; Gerry, M. C. L.
Canadian Journal of Chemistry, 1987 , vol. 65, p. 2478 - 2488
in neat (no solvent, gas phase) Kinetics; byproducts: H2S, HS(1-), OH(1-); in flowing afterglow system at 298 K, at 0,3-0.4 torr and 140-190 cm3/s He; further byproducts: CO, H2O;
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Bierbaum, Veronica M.; Grabowski, Joseph J.; DePuy, Charles H.
Journal of Physical Chemistry, 1984 , vol. 88, # 7 p. 1389 - 1393
