(R)-(-)-2-戊醇合成路线 （共 42 条）
反应条件
Candida antarctica lipase B immobilized on acrylic resin catalyst in pentane T=20 - 25°C; 24 h; Enzymatic reaction; optical yield given as percent eeenantioselective reaction;
参考文献
Strohalm, Hedwig; Dold, Susanne; Pendzialek, Kathrin; Weiher, Monika; Engel, Karl-Heinz
Journal of Agricultural and Food Chemistry, 2010 , vol. 58, # 10 p. 6328 - 6333
反应条件
Candida antarctica lipase B catalyst in n-heptane T=20 - 25°C; 24 h; Enzymatic reaction; optical yield given as percent eeenantioselective reaction;
参考文献
Journal of Agricultural and Food Chemistry, , vol. 58, # 10 p. 6328 - 6333
反应条件
Candida antarctica lipase B catalyst in n-heptane T=20 - 25°C; 24 h; Enzymatic reaction; optical yield given as percent eeenantioselective reaction;
参考文献
Journal of Agricultural and Food Chemistry, , vol. 58, # 10 p. 6328 - 6333
反应条件
hydrogen; platinum(IV) oxide
参考文献
Bulletin de la Societe Chimique de France, , p. 1291 - 1294
反应条件
1: 83 percent / triphenylphosphine, diethyl azodicarboxylate / tetrahydrofuran / 1.5 h / 25 °C 2: 93.5 percent / KOH / methanol; H2O; tetrahydrofuran / 2 h / 25 °C View Scheme
参考文献
Journal of Organic Chemistry USSR (English Translation), , vol. 26, # 9.1 p. 1613 - 1616
Zhurnal Organicheskoi Khimii, , vol. 26, # 9 p. 1864 - 1869
反应条件
1: 80 percent / ZnCl2 / diethyl ether / 1 h / 25 °C 2: 83 percent / triphenylphosphine, diethyl azodicarboxylate / tetrahydrofuran / 1.5 h / 25 °C 3: 93.5 percent / KOH / methanol; H2O; tetrahydrofuran / 2 h / 25 °C View Scheme
参考文献
Journal of Organic Chemistry USSR (English Translation), , vol. 26, # 9.1 p. 1613 - 1616
Zhurnal Organicheskoi Khimii, , vol. 26, # 9 p. 1864 - 1869
反应条件
hydrogen iodide nachfolgende Hydrierung in Gegenwart von kollodialem Palladium;
参考文献
Journal of Biological Chemistry, , vol. 72, p. 594
反应条件
sodium hydroxide; (-)-isopinocampheylborane; dihydrogen peroxide 1) THF, -25 deg C, 9 h, 2) 50 deg C, 1 h; Yield given. Multistep reaction. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Journal of Organic Chemistry, , vol. 46, # 24 p. 5047 - 5048
反应条件
in water T=35 - 37°C; 140 h; Candida cylindracea lipase immobilized on Amberlite IRA-938, pH 7.3; Yield given. Yields of byproduct given;
参考文献
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, , vol. 32, # 1 p. 85 - 87
反应条件
methanol; sodium hydroxide; diisopinocamphenylboron chloride; dihydrogen peroxide 1.) THF, -25 deg C, 4.5 h, 2.) 55 deg C, 1 h; Yield given. Multistep reaction. Yields of byproduct given;
参考文献
Journal of Organic Chemistry, , vol. 47, # 26 p. 5065 - 5069
