(Ph)2SiH2; [rhodium(I)chloride(triphenylphosphine)3] in tetrahydrofuran T=50°C; 6 h;
参考文献
Ohta, Tetsuo; Kamiya, Masahiro; Nobutomo, Mami; Kusui, Keisuke; Furukawa, Isao
Bulletin of the Chemical Society of Japan, 2005 , vol. 78, # 10 p. 1856 - 1861
Jones, William D.; Foster, Glenn P.; Putinas, Jeanne M.
Journal of the American Chemical Society, 1987 , vol. 109, # 16 p. 5047 - 5048
→
反应条件
in toluene stirred for 12 h at room temp. under Ar or for 6 h at 90 ° C; evapd., hexane added, suspn. was filtered to give Ta-complex as a ppt.,soln. was passed through a SiO2 column (eluent THF), evapd.;
参考文献
Royo, Pascual; Sanchez-Nieves, Javier
Journal of Organometallic Chemistry, 2000 , vol. 597, # 1-2 p. 61 - 68
Jousseaume, Bernard; Vilcot, Nathalie; Ricci, Alfredo; Tiekink, Edward R. T.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1994 , # 16 p. 2283 - 2288
Jousseaume, Bernard; Vilcot, Nathalie; Ricci, Alfredo; Tiekink, Edward R. T.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1994 , # 16 p. 2283 - 2288
1: 95 percent / HCl / tetrahydrofuran / 15 h / Ambient temperature 2: 1.) Me3SnLi, 2.) MeLi 3: 82 percent / HCl / tetrahydrofuran / 15 h / Ambient temperature View Scheme
参考文献
Jousseaume, Bernard; Vilcot, Nathalie; Ricci, Alfredo; Tiekink, Edward R. T.
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1994 , # 16 p. 2283 - 2288
