(2,5-二溴噻吩-3-基)甲基磷酸二乙酯合成路线 （共 5 条）
反应条件
hydrogen bromide; bromine in diethyl ether T=0 - 20°C;
参考文献
Collis, Gavin E.; Burrell, Anthony K.; Blandford, Esther J.; Officer, David L.
Tetrahedron, 2007 , vol. 63, # 45 p. 11141 - 11152
反应条件
T=160°C; Arbuzov reaction; 2 h;
参考文献
Hsu, So-Lin; Chen, Chia-Min; Cheng, Yu-Hsin; Wei, Kung-Hwa
Journal of Polymer Science, Part A: Polymer Chemistry, 2011 , vol. 49, # 3 p. 603 - 611
反应条件
1: 85 percent / n-bromosuccinimide / tetrahydrofuran; acetic acid / 1 h / 20 °C 2: 83 percent / n-bromosuccinimide; benzoyl peroxide / CCl4 / 3 h / Heating 3: 2 h / 160 °C View Scheme
参考文献
Hsu, So-Lin; Chen, Chia-Min; Cheng, Yu-Hsin; Wei, Kung-Hwa
Journal of Polymer Science, Part A: Polymer Chemistry, 2011 , vol. 49, # 3 p. 603 - 611
反应条件
1: 83 percent / n-bromosuccinimide; benzoyl peroxide / CCl4 / 3 h / Heating 2: 2 h / 160 °C View Scheme
参考文献
Hou, Jianhui; Yang, Chunhe; He, Chang; Li, Yongfang
Chemical Communications, 2006 , # 8 p. 871 - 873
反应条件
1: 70 percent / tri(tert-butyl)phosphine; K3PO4 / tris(dibenzylideneacetone)dipalladium / tetrahydrofuran / 4 h / Heating
2: 53 percent / KOt-Bu / tetrahydrofuran / 4 h / 20 °C
View Scheme
参考文献
Collis, Gavin E; Burrell, Anthony K; Officer, David L
Tetrahedron Letters, 2001 , vol. 42, # 49 p. 8733 - 8735
