(S)-(-)-丁烯氧化物合成路线 (共 15 条)
反应条件
potassium pentanolate in pentan-1-ol 0.5 h; Ambient temperature;
参考文献
Kim,M.J.; Whitesides,G.M.
Journal of the American Chemical Society, 1988 , vol. 110, p. 2959
反应条件
bis(triphenylphosphine)iminium acetate; C64H74Cl2Co2N4O4 in toluene T=0°C; 52 h; Resolution of racemateInert atmosphere; optical yield given as percent ee;
参考文献
Hirahata, Wataru; Thomas, Renee M.; Lobkovsky, Emil B.; Coates, Geoffrey W.
Journal of the American Chemical Society, 2008 , vol. 130, # 52 p. 17658 - 17659
反应条件
C64H74Cl2Co2N4O4; bis(triphenylphosphoranylidene)-ammonium acetate in toluene T=0°C; 0.233333 h; Product distribution / selectivity;
参考文献
CORNELL RESEARCH FOUNDATION, INC.
Patent: WO2009/26261 A2, 2009 ;
Location in patent: Page/Page column 69-70 ;
反应条件
air; 4-nitro-benzoic acid in various solvent(s) T=20°C; 30 h; Title compound not separated from byproducts;
参考文献
Organic Letters, , vol. 7, # 10 p. 1983 - 1985
反应条件
hydrogenchloride; (R,R)-[Co(salen)]*GaCl3 in diethyl ether T=0 - 4°C; 1 h;
参考文献
Journal of Organometallic Chemistry, , vol. 691, # 9 p. 1862 - 1872
参考文献
Sard; Duffley; Robertson; Razdan
Synthesis, 1984 , vol. NO. 6, p. 506 - 509
反应条件
water; chiral ((substituted salen)Co)2-InCl3 T=20°C; 3 h;
参考文献
Thakur, Santosh Singh; Chen, Shu-Wei; Li, Wenji; Shin, Chang-Kyo; Koo, Yoon-Mo; Kim, Geon-Joong
Synthetic Communications, 2006 , vol. 36, # 16 p. 2371 - 2383
反应条件
Agrobacterium radiobacter halohydrin dehalogenase T=20°C; pH=7.5; 5 h; Tris-SO4 bufferEnzymatic reaction; optical yield given as percent ee;
参考文献
Organic Letters, , vol. 10, # 12 p. 2417 - 2420
反应条件
potassium hydroxide T=25°C; 1 h;
参考文献
Helvetica Chimica Acta, , vol. 87, # 10 p. 2662 - 2684
反应条件
C5H11OK in pentan-1-ol Yield given;
参考文献
Journal of the Chemical Society, Chemical Communications, , # 16 p. 1064 - 1066