5-乙烯基双环[2.2.1]庚-2-烯合成路线 （共 26 条）
反应条件
1: 1.) NaBH4, BF3*O(C2H5)2, 2.)aq. NaOH, 30 percent aq. H2O2 / 1.) THF, RT, 3 h, 2.) THF/H2O, 40 deg C, 3 h 2: 42.1 percent / iodine, potassium iodide, NaHCO3 / dioxane; H2O / 1 h / Ambient temperature 3: 48.7 percent / pyridine / Ambient temperature 4: 55 percent / pyridine / 12 h / Heating View Scheme
参考文献
Bulletin of the Chemical Society of Japan, , vol. 60, p. 1954 - 1956
反应条件
T=130°C; Cycloaddition;
参考文献
Russian Journal of Organic Chemistry, , vol. 34, # 10 p. 1403 - 1409
反应条件
2: (i) nBuLi, (ii) /BRN= 4230481/ View Scheme
参考文献
Journal fuer Praktische Chemie (Leipzig), , vol. 314, p. 467 - 482
反应条件
(i) nBuLi, (ii) /BRN= 4230481/; Multistep reaction;
参考文献
Journal fuer Praktische Chemie (Leipzig), , vol. 314, p. 467 - 482
参考文献
Plate,A.F.; Belikova,N.A.
J. Gen. Chem. USSR (Engl. Transl.), 1960 , vol. 30, p. 3945 - 3953,3902 - 3909
反应条件
T=206°C; Cope Rearrangement; P=10343.2 Torr; 0.666667 h; Pyrolysis; Product distribution / selectivity;
参考文献
US2009/54714 A1, ;
Page/Page column 7 ;
反应条件
T=160 - 180°C; Cope Rearrangement; P=1147.92 - 2311.54 Torr; 17 - 40 h; PyrolysisIndustry scale; Rate constant;
参考文献
US2009/54714 A1, ;
Page/Page column 10-11 ;
反应条件
T=150°C; Cope Rearrangement; 69.6333 h; Pyrolysis; Product distribution / selectivity;
参考文献
US2009/54714 A1, ;
Page/Page column 13-14 ;
反应条件
dihydrogen peroxide; acetic acid in water T=70°C; 6 h; TemperatureReagent/catalystConcentration;
参考文献
Alimardanov, Kh. M.; Garibov; Abdullaeva, M. Ya.; Sadygov; Kuliev; Ismailov
Russian Journal of General Chemistry, 2013 , vol. 83, # 1 p. 63 - 71
Zh. Obshch. Khim., 2013 , vol. 83, # 1 p. 70 - 79,10
反应条件
T=141 - 165°C; Cope Rearrangement; 216 h; Pyrolysis; Product distribution / selectivity;
参考文献
PROMERUS LLC
Patent: US2009/54714 A1, 2009 ;
Location in patent: Page/Page column 14 - 15 ;
