1: ethanol; H2O / 0.5 h / 48 - 50 °C 2: 96 percent / m-chloroperbenzoic acid / CHCl3 / 4 h / Ambient temperature 3: 63 percent / Heating 4: 68 percent / aq. H2SO4 / tetrahydrofuran / 20 h / Heating View Scheme

in acetonitrile T=25°C; Rate constantEquilibrium constant;

1: ethanol; H2O / 0.5 h / 48 - 50 °C 2: 96 percent / m-chloroperbenzoic acid / CHCl3 / 4 h / Ambient temperature 3: 63 percent / Heating 4: 68 percent / aq. H2SO4 / tetrahydrofuran / 20 h / Heating 5: 71 percent / DMSO, N,N'-dicyclohexylcarbodiimide, H3PO4 / 1.5 h / Ambient temperature View Scheme

in acetonitrile T=25°C; Rate constantEquilibrium constant;

1: With ethanol; water T=45 - 50°C; 2 h; 2: in ethanol Product distribution / selectivity;

1: ethanol; H2O / 0.5 h / 48 - 50 °C 2: 96 percent / m-chloroperbenzoic acid / CHCl3 / 4 h / Ambient temperature View Scheme