(Z)-2-溴-2-丁烯合成路线 (共 36 条)
反应条件
calcium hydroxide powder; carbon monoxide; methyl iodide in 1,4-dioxane; water 20°C, 20 h.;
参考文献
Miura, Masahiro; Okuro, Kazumi; Hattori, Ayako; Nomura, Masakatsu
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1989 , p. 73 - 76
反应条件
sodium hypobromide in acetic acid; acetone T=0°C;
参考文献
VanBrunt, Michael P.; Ambenge, Reuben O.; Weinreb, Steven M.
Journal of Organic Chemistry, 2003 , vol. 68, # 8 p. 3323 - 3326
参考文献
Lepingle
Bulletin de la Societe Chimique de France, 1926 , vol. <4>39, p. 757
反应条件
pyridine; N,N'-dimethyl-N,N'-propyleneurea; 4,4'-dimethoxy-2,2'-bipyridine; NiI2*3.5H2O; sodium iodide; zinc T=20 - 60°C; 20 h; chemoselective reaction;
参考文献
Everson, Daniel A.; Jones, Brittany A.; Weix, Daniel J.
Journal of the American Chemical Society, 2012 , vol. 134, # 14 p. 6146 - 6159
反应条件
LiOSiMe3; 9,9-dimethyl-4,5-bis(diphenyl-phosphino)xanthene; bis(dibenzylideneacetone)-palladium(0) in 1,4-dioxane T=80°C; 16 h; Glovebox;
参考文献
Friis, Stig D.; Andersen, Thomas L.; Skrydstrup, Troels
Organic Letters, 2013 , vol. 15, # 6 p. 1378 - 1381
反应条件
diethyl ether; lithium anschliessend mit Kohlendioxid;
参考文献
Bowden, Martin C.; Pattenden, Gerald
Tetrahedron Letters, 1988 , vol. 29, # 6 p. 711 - 714
反应条件
lithium 1) Et2O, 0 deg C, 2h, 2) Et2O, 0 deg C to RT; Yield given. Multistep reaction;
参考文献
Begley, Michael J.; Bowden, Martin C.; Patel, Prakash; Pattenden, Gerald
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1991 , # 8 p. 1951 - 1958
反应条件
potassium hydroxide; hydrogen in water T=45°C; 1.66667 h; Yield given. Yields of byproduct given;
参考文献
Funabiki, Takuzo; Hosomi, Hiroaki; Yoshida, Satohiro; Tarama, Kimio
Journal of the American Chemical Society, 1982 , vol. 104, # 6 p. 1560 - 1568
反应条件
potassium hydroxide; ethylene glycol
T=115°C;
参考文献
Bordwell; Landis
Journal of the American Chemical Society, 1957 , vol. 79, p. 1593,1596
反应条件
tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran
T=35°C; 15 h;
参考文献
Andreini, Bianca Patrizia; Carpita, Adriano; Rossi, Renzo; Scamuzzi, Barbara
Tetrahedron, 1989 , vol. 45, # 17 p. 5621 - 5640