二氯-二(苯基甲基)锡烷合成路线 （共 18 条）
反应条件
in dichloromethane (inert atmosphere); -30°C; solvent removal (vac.), removal of Me3SnCl by sublimation, crystn. (CH2Cl2, -30°C); elem. anal.;
参考文献
Chemische Berichte, , vol. 129, # 2 p. 175 - 189
反应条件
in dichloromethane Kinetics; byproducts: AlCl3; react. under N2, cooling a soln. of (C6H5CH2)2SnCl2 in CH2Cl2, addn. of (C4H9)3Al via syringe (molar ratio = 3:2); hydrolysis with CH2Cl2 satd. with water and then with 1 N HCl, decanting the org. layer, drying, evapn. under vac., incomplete react.;
参考文献
Mahieu, B.; Mestdagh-Peeters, C.; De Laet, M.
Bulletin des Societes Chimiques Belges, 1985 , vol. 94, p. 797 - 804
参考文献
Gmelin Handbook: Sn: Org.Verb.1, 1.1.1.13, page 122 - 129
参考文献
Gmelin Handbook: Sn: Org.Verb.3, 1.1.3.1, page 1 - 24
参考文献
Council of Scientific and Industrial Research
Patent: US5877320 A1, 1999 ;
反应条件
thionyl chloride
from 0 deg C up to room temp.; reflux, 30 min;
参考文献
Narula, Suraj P.; Sharma, R. K.; Lata, Sneh; Walia, Rita
Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1983 , vol. 22, # 3 p. 246 - 247
反应条件
in not given
dropwise addn. of thionyl chloride to tetraalkyltin(IV) compd. under dry N2 atmosphere under ice cooling, warming to room temp., refluxing for 30 min; distn. (removal of excess of SOCl2), cooling resulting liquids, sepn., elem. anal.;
参考文献
Narula, Suraj P.; Sharma, R. K.; Lata, Sneh; Walia, Rita
Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1983 , vol. 22, # 3 p. 246 - 247
反应条件
pyrrolidin-1-yl-2,5-dione in ethanol
byproducts: toluene; treatment with succinimide at 170°C, formation of C6H6 and toluene, treatment of residue with Hcl in ethanol;;
参考文献
Razuvaev, G.; Fetyukova, V.
Zhurnal Obshchei Khimii, 1951 , vol. 21, p. 1107 - 1112
Zhurnal Obshchei Khimii, 1951 , vol. 21, p. 1010 - 1015
反应条件
in benzene-d6
byproducts: bibenzyl; Irradiation (UV/VIS); soln. of the stannane in C6D6 was purged by N2 and irradiated with the light from an excimer laser (308 nm); polystannanes are also formed, mechanism of the photoreaction is proposed; (1)H NMR study;
参考文献
Standt, Adelheit; Dreeskamp, Herbert
Journal of Organometallic Chemistry, 1987 , vol. 322, p. 49 - 56
反应条件
in chloroform-d1
byproducts: bibenzyl, PhCH2CDCl2; Irradiation (UV/VIS); soln. of the stannane in CDCl3 was purged by N2 and irradiated with the light from an excimer laser (308 nm); mechanism of the photoreaction is proposed; (1)H NMR study;
参考文献
Standt, Adelheit; Dreeskamp, Herbert
Journal of Organometallic Chemistry, 1987 , vol. 322, p. 49 - 56
