氯(二甲基硫化)金(I)合成路线 （共 39 条）
反应条件
in dichloromethane
soln. of Pt-complex in CH2Cl2, addn. of Au-complex in CH2Cl2 (0°C), immediate color change from light to dark red, stirred (1 h); solvent removed (dark red solid), not isolated, monitored by NMR;
参考文献
Arsenault, G. J.; Puddephatt, R. J.
Canadian Journal of Chemistry, 1989 , vol. 67, p. 1800 - 1806
反应条件
in dichloromethane
soln. of Pt-complex in CH2Cl2, addn. of Au-complex in CH2Cl2 (0°C), immediate color change from orange to dark red, stirred (5 min, ambient temp.); solvent removed (dark red oil), not isolated, monitored by NMR;
参考文献
Arsenault, G. J.; Puddephatt, R. J.
Canadian Journal of Chemistry, 1989 , vol. 67, p. 1800 - 1806
反应条件
in dichloromethane
under N2; MeNC in CH2Cl2 added dropwise to suspn. of Au complex in CH2Cl2; maintained at room temp. in the absence of light with stirring for 4 h; stored in refrigerator overnight; filtered; ppt. washed with petroleum ether;
参考文献
Heathcote, Robert; Howell, James A. S.; Jennings, Nicola; Cartlidge, David; Cobden, Lisa; Coles, Simon; Hursthouse, Michael
Dalton Transactions, 2007 , # 13 p. 1309 - 1315
反应条件
in chloroform
addn. of excess amine to Au-complex; concn. (vac.), crystn. on Et2O addn. (refrigerator); elem. anal.;
参考文献
Jones, Peter G.; Maddock, Alfred G.; Mays, Martin J.; Muir, Mariel M.; Williams, Alan F.
Journal of the Chemical Society, Dalton Transactions: Inorganic Chemistry (1972-1999), 1977 , p. 1434 - 1439
反应条件
(n)BuLi in diethyl ether; hexane
byproducts: LiCl, Me2S; N2-atmosphere; stirring equimolar amts. of BuLi and alkyne at 0°C, addn. of Au-complex, stirring for 30 min, addn. of Ti-complex, stirring for 2 h at 25°C; evapn., extn. (pentane), filtration (Celite), concn., cooling (0°C); elem. anal.;
参考文献
Koehler, Katrin; Silverio, Sandro J.; Hyla-Kryspin, Isabella; Gleiter, Rolf; Zsolnai, Laszlo; Driess, Alexander; Huttner, Gottfried; Lang, Heinrich
Organometallics, 1997 , vol. 16, # 23 p. 4970 - 4979
反应条件
in dichloromethane
byproducts: Me2S; (protection from light); removal of solvent by passing N2 over the reaction mixture, recrystn. (CH2Cl2/EtOH); elem. anal.;
参考文献
Copley, Royston C. B.; Mingos, D. Michael P.
Journal of the Chemical Society - Dalton Transactions, 1996 , # 4 p. 479 - 489
参考文献
Koehler, Katrin; Silverio, Sandro J.; Hyla-Kryspin, Isabella; Gleiter, Rolf; Zsolnai, Laszlo; Driess, Alexander; Huttner, Gottfried; Lang, Heinrich
Organometallics, 1997 , vol. 16, # 23 p. 4970 - 4979
反应条件
in dichloromethane-d2
To a soln. of Pt(CH3)2(C5H4N)2 is added a soln. of AuCl(S(CH3)2) at -70°C, warming up to -10°C.; Monitored by NMR.;
参考文献
Arsenault, Gilles J.; Anderson, Craig M.; Puddephatt, Richard J.
Organometallics, 1988 , vol. 7, p. 2094 - 2097
反应条件
in neat (no solvent)
byproducts: CH3SSCH3, C2H6, Cl2; thermal decompn. (20-500°C); DTA, DTG, TG;
参考文献
Kokoreva, S. G.; Nifontova, G. A.; Korableva, L. G.; Sikorenko, Yu. B.; Lavrent'ev, I. P.
Russian Journal of Inorganic Chemistry (Translation of Zhurnal Neorganicheskoi Khimii), 1995 , vol. 40, p. 1270 - 1274
Zhurnal Neorganicheskoi Khimii, 1995 , vol. 40, p. 1320 - 1324
