氯(二甲基硫化)金(I)合成路线 （共 39 条）
反应条件
in methanol byproducts: HCl; refluxed for 2 h; concd. under reduced pressure, filtered, washed with CH2Cl2; elem. anal.;
参考文献
Leonesi, Dante; Lorenzotti, Adriana; Cingolani, Augusto; Bonati, Flavio
Gazzetta Chimica Italiana, 1981 , vol. 111, # 11/12 p. 483 - 488
反应条件
in dichloromethane byproducts: Me2S; N2-atmosphere; addn. of equimolar amt. of phosphine to Au-complex soln. over 5 min; in air; pptn. on hexane addn., evapn. (reduced pressure), filtration, recrystn. (CH2Cl2/hexane), drying (vac.); elem. anal.;
参考文献
Mueller, Thomas E.; Green, Jennifer C.; Mingos, D. Michael P.; McPartlin, C. Mary; Whittingham, Conrad; Williams, David J.; Woodroffe, Thomas M.
Journal of Organometallic Chemistry, 1998 , vol. 551, # 1-2 p. 313 - 330
参考文献
Bonati, Flavio; Felici, Marcello; Pietroni, Bianca Rosa; Burini, Alfredo
Gazzetta Chimica Italiana, 1982 , vol. 112, # 1/2 p. 5 - 8
反应条件
in acetone acetone soln. of 2,2'-bis(diphenylphosphino)-1,1'-binaphthyl added to acetone suspn. of AuClSMe2; stirred for 2 h; filtered;washed with acetone, Et2O, pentane; vac. dried; elem. anal.;
参考文献
Wheaton, Craig A.; Jennings, Michael C.; Puddephatt, Richard J.
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 2009 , vol. 64, # 11-12 p. 1469 - 1477
反应条件
in benzene slight excess of the phosphine; evapd., recrystd. from benzene-hexane, IR, elem. anal.;
参考文献
Banditelli, Guido; Bandini, Anna Laura; Bonati, Flavio; Goel, Ram G.; Minghetti, Giovanni
Gazzetta Chimica Italiana, 1982 , vol. 112, p. 539 - 542
反应条件
(C2H5)3N in not given (dark); addn. of Au complex to PhCCH in presence of Et3N; Vicente, J. etal. Inorg. Chim. Acta 2003, 347, 67-74; Siemling, U. et al. Organometal lics 2008, 27 (24), 6419-6426; Vicente, J. et al. Organometallics 2005, 24 (24), 5956-5963;
参考文献
Siemeling, Ulrich; Rother, Dag; Bruhn, Clemens
Organometallics, 2008 , vol. 27, # 24 p. 6419 - 6426
反应条件
in tetrahydrofuran N2 atmosphere; addn. of soln of org. compd. in THF to soln. of Au-compd. in THF (0°C), stirring (15 min), warming (room temp.); concn. (vac.)pptn. on addn. of pentane, filtration, washing (pentane), drying (vac.); elem. anal.;
参考文献
Schmidbaur, Hubert; Brachthaeuser, Benno; Steigelmann, Oliver; Beruda, Holger
Chemische Berichte, 1992 , vol. 125, # 12 p. 2705 - 2710
反应条件
in dichloromethane byproducts: Me2S; N2-atmosphere; addn. of equimolar amt. of phosphine to Au-complex soln. over 5 min; in air; pptn. on hexane addn., evapn. (reduced pressure), filtration, recrystn. (CH2Cl2/hexane), drying (vac.); elem. anal.;
参考文献
Mueller, Thomas E.; Green, Jennifer C.; Mingos, D. Michael P.; McPartlin, C. Mary; Whittingham, Conrad; Williams, David J.; Woodroffe, Thomas M.
Journal of Organometallic Chemistry, 1998 , vol. 551, # 1-2 p. 313 - 330
反应条件
in dichloromethane T=22°C; 3 h; Inert atmosphereSchlenk technique;
参考文献
Fourmy, Kevin; Mallet-Ladeira, Sonia; Dechy-Cabaret, Odile; Gouygou, Maryse
Organometallics, 2013 , vol. 32, # 6 p. 1571 - 1574
反应条件
in acetone
addn. of soln. of dppm (1 equiv.) in acetone to suspn. of (AuCl(SMe)2) (2 equiv.) in acetone; stirring for 2 h; pptn., filtration, washing with acetone, diethyl ether and pentane, drying under vac.;
参考文献
Brandys, Marie-Claude; Jennings, Michael C.; Puddephatt, Richard J.
Journal of the Chemical Society, Dalton Transactions, 2000 , # 24 p. 4601 - 4606
