5H-二苯并[a,d]环庚烯合成路线 （共 24 条）
反应条件
hydrogenchloride in methanol
0.5 h;
参考文献
Rothauser Lamanec; Bender; DeMarco; Karady; Reamer; Weinstock
Journal of Organic Chemistry, 1988 , vol. 53, # 8 p. 1768 - 1774
反应条件
methyllithium in diethyl ether; dichloromethane; water
参考文献
Merck Sharp and Dohme Limited
Patent: US4927819 A1, 1990 ;
反应条件
2: iodine
View Scheme
参考文献
Franco, M. Luisa T. M. B.; Lazana, M. Celina R. L. R.
Journal of the Chemical Society, Faraday Transactions, 1994 , vol. 90, # 21 p. 3273 - 3280
反应条件
1: pyridine; SOCl2
2: potassium ethylate / 135 °C
View Scheme
参考文献
Rigaudy; Tardieu
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1959 , vol. 248, p. 1538
反应条件
n-butyllithium in diethyl ether
5 h; Heating;
参考文献
Fujiwara; Sumino; Nozaki; Okamoto
Chemical and Pharmaceutical Bulletin, 1989 , vol. 37, # 6 p. 1452 - 1457
反应条件
1: bromine / Irradiation
3: concentrated H2SO4; methanol
View Scheme
参考文献
Treibs; Klinkhammer
Chemische Berichte, 1951 , vol. 84, p. 671,679
反应条件
pentacarbonyl(η2-cis-cyclooctene)chromium(0) in dichloromethane
16 h; Ambient temperature;
参考文献
Pfeiffer, Juergen; Nieger, Martin; Doetz, Karl Heinz
European Journal of Organic Chemistry, 1998 , # 6 p. 1011 - 1022
反应条件
1: anschliessend Behandeln mit Silberbenzoat und tert-Butylalkohol
2: toluene-4-sulfonic acid; benzene
3: polyphosphoric acid
4: NaBH4; methanol; aqueous NaOH
5: H3BO3 / 205 °C / 0.5 Torr
6: CCl4; N-bromo-succinimide
7: 2-methyl-pyridine
View Scheme
参考文献
Cope; Smith
Journal of the American Chemical Society, 1955 , vol. 77, p. 4596,4598
参考文献
Cope; Smith
Journal of the American Chemical Society, 1955 , vol. 77, p. 4596,4598
参考文献
Cope; Smith
Journal of the American Chemical Society, 1955 , vol. 77, p. 4596,4598
