in benzene compds. stirred together in refluxing benzene for 3 h; cooled to room temp., filtered, washed with benzene to give PhTe(NPPh3)Cl2, combined filtrate and washings concd. to give Ph3SbCl2;
参考文献
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, , vol. 12, p. 47 - 54
in benzene oximate in benzene was added to PhTeCl3 in benzene, mixt. was refluxed (ca. 4 h); filtered, washed with benzene, filtrate and washings were concd.;
参考文献
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, , vol. 11, p. 7 - 14
in benzene compds. stirred together in refluxing benzene for 3 h; cooled to room temp., filtered, washed with benzene to give PhTe(NPPh3)Cl2, combined filtrate and washings concd. to give Ph3GeCl;
参考文献
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, , vol. 12, p. 47 - 54
1: 6 h / 145 - 160 °C
2: hydrated Na2S
View Scheme
参考文献
Srivastava, T. N.; Srivastava, R. C.; Singh, Mala
Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1980 , vol. 19, # 5 p. 435 - 437
