2-甲基-6-硝基苯并噻唑合成路线 （共 15 条）
反应条件
sulfuric acid; nitric acid T=0 - 20°C;
参考文献
Hrobarikova, Veronika; Hrobarik, Peter; Gajdos, Peter; Fitilis, Ioannis; Fakis, Mihalis; Persephonis, Peter; Zahradnik, Pavol
Journal of Organic Chemistry, 2010 , vol. 75, # 9 p. 3053 - 3068
反应条件
1: With copper(l) iodide; Na2S*9H2O in N,N-dimethyl-formamide T=80°C; 12 h; 2: With hydrogenchloride in N,N-dimethyl-formamide T=20°C;
参考文献
Ma, Dawei; Xue, Peng; Jiang, Yongwen; Xie, Siwei; Zhang, Xiaojing; Dong, Jinhua
Angewandte Chemie, International Edition, 2009 , vol. 48, # 23 p. 4222 - 4225
反应条件
N(Et)4ClO4 in acetonitrile (electrochemical cyclodehydrogenation);
参考文献
Tabakovic,I. et al.
Synthesis, 1979 , p. 590 - 592
反应条件
(i) P2S5, (ii) K3<Fe(CN)6>; Multistep reaction;
参考文献
Mohanty,S. et al.
Indian Journal of Chemistry, 1968 , vol. 6, p. 136 - 139
参考文献
Mylius
Dissertation <Berlin 1883>, S. 48
反应条件
1: tin; aqueous HCl 2: Diazotierung und Umsetzung mit CuCl View Scheme
参考文献
Mizuno; Adachi
Yakugaku Zasshi, 1952 , vol. 72, p. 739,742
反应条件
1.1: 86 percent / Fe; aq. HCl / ethanol / 0.33 h / 90 °C / sonification 2.1: aq. H2SO4; NaNO2 / -2 - 2 °C 2.2: 57 percent / CuCN; aq. NaOH / 0.17 h / 20 °C View Scheme
参考文献
Caleta; Grdisa; Mrvos-Sermek; Cetina; Tralic-Kulenovic; Pavelic; Karminski-Zamola
Farmaco, 2004 , vol. 59, # 4 p. 297 - 305
参考文献
Hamer et al.
Journal of the Chemical Society, 1947 , p. 954,956
反应条件
dihydrogen peroxide in sodium hydroxide
参考文献
Bayer Aktiengesellschaft
Patent: US4548761 A1, 1985 ;
反应条件
1.1: 92 percent / HCOONH2 / Pd/C / tetrahydrofuran; methanol / 72 h / 20 °C 2.1: aq. HCl; NaNO2 / 0.5 h / cooling 2.2: 79 percent / aq. KI / H2O / 0.17 h / 40 °C View Scheme
参考文献
Helvetica Chimica Acta, , vol. 88, # 5 p. 1135 - 1143
