3,7-二甲基-6-辛烯-1-炔基-3-醇合成路线 （共 58 条）
反应条件
benzoic acid; bis(2-methylpropenyl)(1,2-bis(diphenylphosphino)ethane)ruthenium in toluene
1.) 70 deg C, 2 h, 2.) 100 deg C, 15 h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Picquet, Michel; Bruneau, Christian; Dixneuf, Pierre H.
Chemical Communications, 1997 , # 13 p. 1201 - 1202
反应条件
(1,4-bis(diphenylphosphino)butane)bis(.eta.(3)-2-methylallyl)ruthenium(II) in toluene
参考文献
Picquet, Michel; Bruneau, Christian; Dixneuf, Pierre H.
Chemical Communications, 1997 , # 13 p. 1201 - 1202
反应条件
1: phosphoric acid
2: silver acetate
View Scheme
参考文献
Saucy et al.
Helvetica Chimica Acta, 1959 , vol. 42, p. 1945,1954
反应条件
toluene-4-sulfonic acid; hydroquinone in Petroleum ether
T=80°C; Claisen rearrangement; 16 h;
参考文献
Snowden, Roger L.; Linder, Simon
Helvetica Chimica Acta, 2006 , vol. 89, # 12 p. 3071 - 3086
反应条件
[Et3NH]+HSO4-
T=95°C; Saucy-Marbet reaction; 24 h;
参考文献
Wang, Congmin; Zhao, Wenjia; Li, Haoran; Guo, Liping
Green Chemistry, 2009 , vol. 11, # 6 p. 843 - 847
反应条件
potassium hydrogensulfate
3 h; Heating;
参考文献
Zakharova,N.I. et al.
Doklady Chemistry, 1968 , vol. 181, p. 654 - 657
Doklady Akademii Nauk SSSR, 1968 , vol. 181, # 3 p. 603 - 606
反应条件
1: beim Kochen
2: coppered zinc dust; diluted alcohol
View Scheme
参考文献
Rupe; Lang
Helvetica Chimica Acta, 1929 , vol. 12, p. 1140
反应条件
sodium hydride in N,N-dimethyl-formamide
T=0°C; 1 h;
参考文献
Wei, Heng-Xu; Schlosser, Manfred
Chemistry - A European Journal, 1998 , vol. 4, # 9 p. 1738 - 1743
反应条件
1: 40 percent / nBuLi
2: 61 percent / MeLi / diethyl ether / -70 °C
View Scheme
参考文献
Cutting, Ian; Parsons, Philip J.
Journal of the Chemical Society, Chemical Communications, 1983 , # 21 p. 1209 - 1210
反应条件
1: beim Kochen
2: permanganate; natrium carbonate
View Scheme
参考文献
Rupe; Lang
Helvetica Chimica Acta, 1929 , vol. 12, p. 1140
