槲皮素 3,4'-二葡糖甙合成路线 (共 9 条)
反应条件
1: potassium carbonate / N,N-dimethyl-formamide / 10 h / 20 °C / |Inert atmosphere 2: hydrogenchloride / water / 2 h / 80 °C 3: potassium carbonate / N,N-dimethyl-formamide / 6 h / 20 °C 4: sodium methylate / methanol; tetrahydrofuran / 6 h / 20 °C 5: palladium 10 on activated carbon; hydrogen / tetrahydrofuran; ethanol / 2 h / 20 °C / 750.08 Torr 6: potassium carbonate / N,N-dimethyl-formamide / 6 h / 20 °C 7: potassium carbonate / N,N-dimethyl-formamide / 10 h / 20 °C / |Inert atmosphere 8: sodium methylate / methanol; tetrahydrofuran / 6 h / 20 °C 9: palladium 10 on activated carbon; hydrogen / tetrahydrofuran; ethanol / 2 h / 20 °C / 750.08 Torr View Scheme
参考文献
Yamauchi, Kosei; Mitsunaga, Tohru; Batubara, Irmanida
Bioorganic and Medicinal Chemistry, 2014 , vol. 22, # 3 p. 937 - 944
反应条件
1: potassium carbonate / N,N-dimethyl-formamide / 6 h / 20 °C 2: sodium methylate / methanol; tetrahydrofuran / 6 h / 20 °C 3: palladium 10 on activated carbon; hydrogen / tetrahydrofuran; ethanol / 2 h / 20 °C / 750.08 Torr 4: potassium carbonate / N,N-dimethyl-formamide / 6 h / 20 °C 5: potassium carbonate / N,N-dimethyl-formamide / 10 h / 20 °C / |Inert atmosphere 6: sodium methylate / methanol; tetrahydrofuran / 6 h / 20 °C 7: palladium 10 on activated carbon; hydrogen / tetrahydrofuran; ethanol / 2 h / 20 °C / 750.08 Torr View Scheme
参考文献
Yamauchi, Kosei; Mitsunaga, Tohru; Batubara, Irmanida
Bioorganic and Medicinal Chemistry, 2014 , vol. 22, # 3 p. 937 - 944
反应条件
1: sodium methylate / methanol; tetrahydrofuran / 6 h / 20 °C 2: palladium 10 on activated carbon; hydrogen / tetrahydrofuran; ethanol / 2 h / 20 °C / 750.08 Torr 3: potassium carbonate / N,N-dimethyl-formamide / 6 h / 20 °C 4: potassium carbonate / N,N-dimethyl-formamide / 10 h / 20 °C / |Inert atmosphere 5: sodium methylate / methanol; tetrahydrofuran / 6 h / 20 °C 6: palladium 10 on activated carbon; hydrogen / tetrahydrofuran; ethanol / 2 h / 20 °C / 750.08 Torr View Scheme
参考文献
Yamauchi, Kosei; Mitsunaga, Tohru; Batubara, Irmanida
Bioorganic and Medicinal Chemistry, 2014 , vol. 22, # 3 p. 937 - 944
反应条件
1: palladium 10 on activated carbon; hydrogen / tetrahydrofuran; ethanol / 2 h / 20 °C / 750.08 Torr 2: potassium carbonate / N,N-dimethyl-formamide / 6 h / 20 °C 3: potassium carbonate / N,N-dimethyl-formamide / 10 h / 20 °C / |Inert atmosphere 4: sodium methylate / methanol; tetrahydrofuran / 6 h / 20 °C 5: palladium 10 on activated carbon; hydrogen / tetrahydrofuran; ethanol / 2 h / 20 °C / 750.08 Torr View Scheme
参考文献
Yamauchi, Kosei; Mitsunaga, Tohru; Batubara, Irmanida
Bioorganic and Medicinal Chemistry, 2014 , vol. 22, # 3 p. 937 - 944
反应条件
1: potassium carbonate / N,N-dimethyl-formamide / 6 h / 20 °C 2: potassium carbonate / N,N-dimethyl-formamide / 10 h / 20 °C / |Inert atmosphere 3: sodium methylate / methanol; tetrahydrofuran / 6 h / 20 °C 4: palladium 10 on activated carbon; hydrogen / tetrahydrofuran; ethanol / 2 h / 20 °C / 750.08 Torr View Scheme
参考文献
Yamauchi, Kosei; Mitsunaga, Tohru; Batubara, Irmanida
Bioorganic and Medicinal Chemistry, 2014 , vol. 22, # 3 p. 937 - 944
反应条件
1: potassium carbonate / N,N-dimethyl-formamide / 6 h / 20 °C 2: potassium carbonate / N,N-dimethyl-formamide / 10 h / 20 °C / |Inert atmosphere 3: sodium methylate / methanol; tetrahydrofuran / 6 h / 20 °C 4: palladium 10 on activated carbon; hydrogen / tetrahydrofuran; ethanol / 2 h / 20 °C / 750.08 Torr View Scheme
参考文献
Yamauchi, Kosei; Mitsunaga, Tohru; Batubara, Irmanida
Bioorganic and Medicinal Chemistry, 2014 , vol. 22, # 3 p. 937 - 944
反应条件
T=30°C; 336 h; cell suspension culture of Vitis hybrid; Yield given. Further byproducts given. Yields of byproduct given;
参考文献
Kodama, Tohru; Ishida, Hidekatsu; Kokubo, Tetsuro; Yamakawa, Takashi; Noguchi, Hiroshi
Agricultural and Biological Chemistry, 1990 , vol. 54, # 12 p. 3283 - 3288
反应条件
T=30°C; 336 h; cell suspension culture of Vitis hybrid; Yield given. Further byproducts given. Yields of byproduct given;
参考文献
Kodama, Tohru; Ishida, Hidekatsu; Kokubo, Tetsuro; Yamakawa, Takashi; Noguchi, Hiroshi
Agricultural and Biological Chemistry, 1990 , vol. 54, # 12 p. 3283 - 3288
反应条件
T=30°C; 336 h; cell suspension culture of Vitis hybrid; Yield given. Further byproducts given. Yields of byproduct given;
参考文献
Kodama, Tohru; Ishida, Hidekatsu; Kokubo, Tetsuro; Yamakawa, Takashi; Noguchi, Hiroshi
Agricultural and Biological Chemistry, 1990 , vol. 54, # 12 p. 3283 - 3288