1-(1-甲基环己基)乙酮合成路线 （共 27 条）
反应条件
(i) PCl5, benzene, (ii) KOH, diethylene glycol, Et2O; Multistep reaction;
参考文献
Brown,R.F.C. et al.
Australian Journal of Chemistry, 1977 , vol. 30, p. 1757 - 1767
参考文献
Meerwein; Schaefer
Journal fuer Praktische Chemie (Leipzig), 1922 , vol. <2> 104, p. 306
参考文献
Meerwein
Justus Liebigs Annalen der Chemie, 1913 , vol. 396, p. 242
Justus Liebigs Annalen der Chemie, 1914 , vol. 405, p. 174
反应条件
in diethyl ether
T=0 - 25°C; 4.5 h;
参考文献
Stulgies, Balder; Prinz, Peter; Magull, Joerg; Rauch, Karsten; Meindl, Kathrin; Ruehl, Stephan; De Meijere, Armin
Chemistry - A European Journal, 2005 , vol. 11, # 1 p. 308 - 320
反应条件
1: in diethyl ether
T=0 - 20°C; 4.5 h; Inert atmosphere;
2: With hydrogenchloride in diethyl ether; water
Inert atmosphereCooling with ice;
参考文献
Tsubo, Tatsuyuki; Chen, Hsiu-Hui; Yokomori, Minako; Fukui, Kosuke; Kikuchi, Satoshi; Yamada, Tohru
Chemistry Letters, 2012 , vol. 41, # 8 p. 780 - 782
参考文献
Tarbouriech
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1909 , vol. 149, p. 862
Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1910 , vol. 150, p. 1606
反应条件
nickel
Hydrogenation;
参考文献
Jacquier et al.
Bulletin de la Societe Chimique de France, 1956 , p. 1653,1664
反应条件
1: K2CO3 / benzyltriethylammonium chloride / benzene
2: aq. KMnO4, KOH, MgSO4 / methanol / 1.) r.t., 2. ) reflux
3: 30 percent Chromat. / Zn<Hg>, aq. HCl / 1.5 h / Heating
View Scheme
参考文献
Bailey, Karen E.; Davis, Brian R.
Australian Journal of Chemistry, 1995 , vol. 48, # 11 p. 1827 - 1834
参考文献
Pines; Marechal
Journal of the American Chemical Society, 1955 , vol. 77, p. 2819,2821
反应条件
sodium hydroxide
24 h; Ambient temperature;
参考文献
Sakai, Takashi; Katayama, Tsuyoshi; Takeda, Akira
Journal of Organic Chemistry, 1981 , vol. 46, # 14 p. 2924 - 2931
