Hegelmann, Ina; Beck, Alexander; Eichhorn, Christian; Weibert, Bernhard; Burzlaff, Nicolai
European Journal of Inorganic Chemistry, 2003 , # 2 p. 339 - 347
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反应条件
in dichloromethane
soln. of dppe was added to a stirred soln. of (Mo(H2CPz'2)(CO)2(π-allyl)Br); reaction was monitored by IR-spectroscopy (every 10 min);; evapn. of solvent (vac.); recrystn. from CH2Cl2/MeOH;;
in dichloromethane
soln. of dppm was added to a stirred soln. of (Mo(H2CPz'2)(CO)2(π-allyl)Br); reaction was monitored by IR-spectroscopy (every 10 min);; evapn. of solvent (vac.); recrystn. from CH2Cl2/MeOH;;
in tetrahydrofuran
soln. of PMe3 was added to a stirred soln. of (Mo(H2CPz'2)(CO)2(π-allyl)Br); reaction was monitored by IR-spectroscopy (every 10 min); stopped after 14 h;; evapn. of solvent (vac.); (Mo(P(CH3)3)2(CO)2(C3H5)Br) is recrystd. from CH2Cl2/MeOH; elem. anal;;
in tetrahydrofuran
soln. of PMe3 was added to a stirred soln. of (Mo(H2CPz'2)(CO)2Br2); reaction was monitored by IR-spectroscopy (every 10 min);; evapn. of solvent (vac.); recrystn. from CH2Cl2/MeOH;;
