lithium aluminium tetrahydride in diethyl ether prepared by LiAlH4 reduction of the corresponding trichlorogermane in Et2O; identified by NMR spectrum;
参考文献
Batchelor,R.J.; Birchall,T.
Journal of the American Chemical Society, 1983 , vol. 105, p. 3848
lithium aluminium tetrahydride in neat (no solvent) byproducts: N2, ClCH2CO2CH2CH3, C6H5COCH2CO2C2H5; 1 equiv of diazoester adding to an equimolar mixt. of Ge deriv. and PhCHO to result in an exothermic reaction with N2 evolution; supentatant treating with LiAlH4 in ether; analyzed by gas chromy. and NMR spectroscopy;
参考文献
Castel, A.; Riviere, P.; Satge, J.
Journal of Organometallic Chemistry, 1982 , vol. 232, # 2 p. 137 - 146
lithium aluminium tetrahydride; acetaldehyde; triethylamine in diethyl ether byproducts: ethanol; 1 equiv of diazoester adding to a mixt. of equimolar amts. of Ge deriv.and acetaldehyde at 0°C then treating with an excess of LiAlH4 in Et2O; analyzed by gas chromy. and NMR spectroscopy;
参考文献
Castel, A.; Riviere, P.; Satge, J.
Journal of Organometallic Chemistry, 1982 , vol. 232, # 2 p. 137 - 146
in neat (no solvent) byproducts: N2, ClCH2CO2CH2CH3; 1 equiv of diazoester adding slowly to an equimolar mixt. of Ge and Sn deriv. to result in exothermic reaction with N2 evolution; after 4 h at 20°C concg., diene ligand adding, heating in a sealed tube for 12h at 120°C; analyzed by gas chromy. and NMR spectroscopy;
参考文献
Castel, A.; Riviere, P.; Satge, J.
Journal of Organometallic Chemistry, 1982 , vol. 232, # 2 p. 137 - 146
lithium aluminium tetrahydride in diethyl ether byproducts: C6H5CH2OH, C6H6; Ge deriv. and benzoic anhydryde heating for 12 h at 85°C in a sealed tube, cooling, treating with an excess of LiAlH4 in ether at 0°C, hydrolyzing, drying over Na2SO4; not isolated; identified by NMR spectra;
参考文献
Castel, A.; Riviere, P.; Satge, J.
Journal of Organometallic Chemistry, 1982 , vol. 232, # 2 p. 137 - 146
in further solvent(s) (Ar); Ge-compound added to a suspn. of LiAlH4 in ethyl ether; stirred for 12-72 h at room temp.; decanted; added water; washed with water; dried; filtered; evapd.; distd.;
参考文献
Clark, K. Brady; Griller, David
Organometallics, 1991 , vol. 10, p. 746 - 750
