1: methyllithium With manganese (II) chloride in tetrahydrofuran
T=0 - 20°C; 1 h;
2: 1,5-pentandioyl chloride With copper(l) chloride in tetrahydrofuran
T=20°C;
参考文献
Chanteau, Stephanie H.; Tour, James M.
Journal of Organic Chemistry, 2003 , vol. 68, # 23 p. 8750 - 8766
1: 100 percent / triethylamine / CH2Cl2 / 2.5 h / 0 - 20 °C
2: 96 percent / ethylmagnesium bromide / diethyl ether; tetrahydrofuran / 2 h / 0 - 20 °C
View Scheme
参考文献
Canonica; Bacchetti
Atti della Accademia Nazionale dei Lincei, Classe di Scienze Fisiche, Matematiche e Naturali, Rendiconti, 1951 , vol. <8> 11, p. 275,279