2-甲基-9H-芴-9-酮合成路线 （共 34 条）
反应条件
CsO2CCMe3; [Pd(P{(C6H11)3})2] in N,N-dimethyl-formamide
T=110°C; Carbonylation; cyclization; P=760.051 Torr; 7 h;
参考文献
Campo, Marino A.; Larock, Richard C.
Journal of Organic Chemistry, 2002 , vol. 67, # 16 p. 5616 - 5620
反应条件
tert.-butylhydroperoxide; biscyclopentadienyliron(II) in decane; acetonitrile
T=20 - 90°C; 24 h; SolventReagent/catalystTemperature;
参考文献
Wertz, Sebastian; Leifert, Dirk; Studer, Armido
Organic Letters, 2013 , vol. 15, # 4 p. 928 - 931
反应条件
dichloro bis(acetonitrile) palladium(II); water; silver trifluoroacetate in N,N-dimethyl acetamide; trifluoroacetic acid
T=140°C; Heck Reaction; 72 h; GloveboxInert atmosphere;
参考文献
Wan, Jung-Chih; Huang, Jun-Min; Jhan, Yu-Huei; Hsieh, Jen-Chieh
Organic Letters, 2013 , vol. 15, # 11 p. 2742 - 2745
反应条件
palladium diacetate; potassium carbonate; trifluoroacetic acid; silver(l) oxide
T=140°C; Nazarov Cyclization; 24 h; Schlenk techniqueInert atmosphere;
参考文献
Li, Hu; Zhu, Ru-Yi; Shi, Wen-Juan; He, Ke-Han; Shi, Zhang-Jie
Organic Letters, 2012 , vol. 14, # 18 p. 4850 - 4853,4
反应条件
1: Na2CO3 / Pd(OAc)2 / dimethylformamide; H2O / 12 h / 25 °C
2: MgSO4 / toluene / 100 °C
3: cesium pivalate / Pd(OAc)2; 1,1-bis(diphenylphosphino)methane / dimethylformamide / 4 h / 100 °C
4: aq. HCl / acetone
View Scheme
参考文献
Zhao, Jian; Yue, Dawei; Campo, Marino A.; Larock, Richard C.
Journal of the American Chemical Society, 2007 , vol. 129, # 16 p. 5288 - 5295
反应条件
1: Na2CO3 / Pd(OAc)2 / dimethylformamide; H2O / 12 h / 25 °C
2: MgSO4 / toluene / 100 °C
3: cesium pivalate / Pd(OAc)2; 1,1-bis(diphenylphosphino)methane / dimethylformamide / 4 h / 100 °C
4: aq. HCl / acetone
View Scheme
参考文献
Zhao, Jian; Yue, Dawei; Campo, Marino A.; Larock, Richard C.
Journal of the American Chemical Society, 2007 , vol. 129, # 16 p. 5288 - 5295
反应条件
cesium fluoride; tris-(o-tolyl)phosphine; bis(dibenzylideneacetone)-palladium(0) in toluene; acetonitrile
T=110°C; 12 h;
参考文献
Zhang, Xiaoxia; Larock, Richard C.
Organic Letters, 2005 , vol. 7, # 18 p. 3973 - 3976
反应条件
sodium acetate; palladium diacetate; triphenylphosphine in N,N-dimethyl-formamide
T=120°C; Suzuki coupling; 16 h; Inert atmosphere;
参考文献
Paul, Sunanda; Samanta, Shubhankar; Ray, Jayanta K.
Tetrahedron Letters, 2010 , vol. 51, # 42 p. 5604 - 5608
反应条件
air; graphene-supported KOH composite in N,N-dimethyl-formamide
T=20°C; 16 h;
参考文献
Zhang, Xin; Ji, Xuan; Su, Ruifei; Weeks, Brandon L.; Zhang, Zhao; Deng, Songlu
ChemPlusChem, 2013 , vol. 78, # 7 p. 703 - 711
反应条件
hydrogenchloride; water
T=100°C; 8 h;
参考文献
Thirunavukkarasu, Vedhagiri S.; Parthasarathy, Kanniyappan; Cheng, Chien-Hong
Angewandte Chemie - International Edition, 2008 , vol. 47, # 49 p. 9462 - 9465
