chloroform in chloroform heating of 5-Cl-2,4-C2B5H6 and CH3Cl in a react. vessel at 126°Cfor 21.0 h; further products; cold-column vac. fractionation at -104 to -29°C; identification by (11)B-NMR;
trimethylamine in dichloromethane
addn. of trimethylamine to B compd.; addn. of fluoride; allowing to stand at room temp., 47d; monitoring by 11B NMR; 25percent 5-ClC2B5H6 obtained;
参考文献
Ng, Bradford; Onak, Thomas; Fuller, Keith
Inorganic Chemistry, 1985 , vol. 24, p. 4371 - 4376
chloroform in chloroform
heating of 5-Cl-2,4-C2B5H6 and CH3Cl in a react. vessel at 126°Cfor 21.0 h; further products; cold-column vac. fractionation at -104 to -29°C; identification by (11)B-NMR;
