9,9-二甲基-2-溴芴合成路线 （共 17 条）
反应条件
bromine; anhydrous iron chloride in water T=20°C; 13 h; Heating / reflux;
参考文献
Idemitsu Kosan Co., Ltd.
Patent: EP1533289 A1, 2005 ;
Location in patent: Page/Page column 22 ;
反应条件
1: 2-Bromofluorene With potassium tert-butylate in tetrahydrofuran T=0°C; 0.166667 h; 2: methyl iodide in tetrahydrofuran T=0 - 20°C;
参考文献
Kobin, Bjoern; Grubert, Lutz; Blumstengel, Sylke; Henneberger, Fritz; Hecht, Stefan
Journal of Materials Chemistry, 2012 , vol. 22, # 10 p. 4383 - 4390
反应条件
1: With n-butyllithium in tetrahydrofuran T=-78°C; 2: With boric acid trimethyl ester in tetrahydrofuran 0.5 h; 3: With hydrogenchloride; water in tetrahydrofuran T=20°C; 1 h;
参考文献
LG Chem, Ltd.
Patent: EP2343277 A2, 2011 ;
Location in patent: Page/Page column 35-36 ;
反应条件
1: 2-bromo-9,9-dimethyl-9H-fluorene With n-butyllithium in tetrahydrofuran; hexane T=-78°C; 1 h; Inert atmosphereCooling with ethanol-dry ice; 2: boric acid trimethyl ester in tetrahydrofuran; hexane T=-78°C; 4 h; Inert atmosphere; 3: With hydrogenchloride in tetrahydrofuran; hexane T=0°C; 6 h;
参考文献
Huang, Hai-Fang; Xu, Shi-Hua; He, Yan-Bo; Zhu, Cai-Cai; Fan, He-Liang; Zhou, Xue-Hua; Gao, Xi-Cun; Dai, Yan-Feng
Dyes and Pigments, 2013 , vol. 96, # 3 p. 705 - 713
反应条件
1: 2-bromo-9,9-dimethyl-9H-fluorene With n-butyllithium in tetrahydrofuran; hexane T=-78°C; 1 h; Inert atmosphere; 2: 2-isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane in tetrahydrofuran; hexane T=20°C; 12 h; Inert atmosphere;
参考文献
Park, Byung Sun; El-deeb, Ibrahim M.; Yoo, Kyung Ho; Han, Dong Keun; Tae, Jin Sung; Lee, So Ha
Bulletin of the Korean Chemical Society, 2012 , vol. 33, # 11 p. 3629 - 3634
反应条件
sulfuric acid; iodine; acetic acid; periodic acid in water T=50°C; 5 h;
参考文献
Samsung Mobile Display Co., Ltd.
Patent: EP2292603 A1, 2011 ;
Location in patent: Page/Page column 24 ;
反应条件
(i) Mg, BrCH2CH2Br, (ii) /BRN= 1900390/; Multistep reaction;
参考文献
Hallas,G. et al.
Journal of the Chemical Society [Section] B: Physical Organic, 1970 , p. 975 - 979
反应条件
tri-tert-butyl phosphine; sodium t-butanolate; palladium diacetate in toluene T=100°C; 12 h;
参考文献
ROHM AND HAAS ELECTRONIC MATERIALS KOREA LTD; LEE, Soo Young; CHO, Young Jun; KIM, Bong Ok; KIM, Sung Min
Patent: WO2012/15265 A1, 2012 ;
Location in patent: Page/Page column 14 ;
反应条件
copper(l) iodide; ammonia; caesium carbonate in water; N,N-dimethyl-formamide; acetylacetone T=100°C; 12 h;
参考文献
Idemitsu Kosan Co., Ltd.
Patent: EP2468725 A1, 2012 ;
反应条件
sodium t-butanolate; tris-(dibenzylideneacetone)dipalladium(0); tri-tert-butyl phosphine in toluene T=90°C; 3 h;
参考文献
Samsung Mobile Display Co., Ltd.
Patent: EP2149555 A1, 2010 ;
Location in patent: Page/Page column 20 ;
