methyl-magnesium iodide in benzene
to PhGeCl in C6H6 (Ph3Ge)2Hg was added, 2 h at 120°C, BrCH2CH2Brwas added, then CH3MgI; products were not sept; analyzed by cpv;
参考文献
Riviere, P.; Castel, A.; Satge, J.; Cazes, A.
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1981 , vol. 11, p. 443 - 454
in cyclohexane
Irradiation (UV/VIS); dissolution of digermane in dry cyclohexane in a quartz tube, degassing in a vacuum, charging with argon, irradiation with a 110 W low pressure Hg arc lamp at room temp. for 2 h; verrifying the photoproducts by GLC and GC-MS;
参考文献
Mochida, Kunio; Wakasa, Masanobu; Sakaguchi, Yoshio; Hayashi, Hisaharu
Bulletin of the Chemical Society of Japan, 1991 , vol. 64, # 6 p. 1889 - 1895
methyl-magnesium iodide in tetrahydrofuran
GeF2 and (Ph3Ge)2Hg in THF, stirring for 12 h at ambient temp., treatingof mixt. with MeMgI; mixt. was hydrolysed, extracted, dried, products were not sepd.; analyzed by cpv;
参考文献
Riviere, P.; Castel, A.; Satge, J.; Cazes, A.
Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1981 , vol. 11, p. 443 - 454
in hexane
Irradiation (UV/VIS); further products; (Ar); SiGe compd. in hexane was mixed with 1,3-dimethyl-2,3-butadiene; photolyzed for 1 h in quartz sealed tubes; GC, GC/MS, PMR monitoring; not isolated;
参考文献
Leigh, William J.; Toltl, Nicholas P.; Apodaca, Paula; Castruita, Madeli; Pannell, Keith H.
Organometallics, 2000 , vol. 19, # 16 p. 3232 - 3241
