in neat (no solvent) Irradiation (UV/VIS); Ge deriv. and a large excess of organic reagent irradiating in a quartztube for 4 h then concg. in vacuo; identified by high-pressure chromy. and NMR spectra;
参考文献
Riviere, P.; Castel, A.; Satge, J.; Guyot, D.
Journal of Organometallic Chemistry, 1984 , vol. 264, # 1-2 p. 193 - 206
Kraus; Foster
Journal of the American Chemical Society, 1927 , vol. 49, p. 466
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Morgan; Drew
Journal of the Chemical Society, 1925 , vol. 127, p. 1760,1763,1765
in neat (no solvent) High Pressure; pressure react. of dry HCl and Ph6Ge2 in autoclave (molar ratio HCl/Ph6Ge2 = 7.3), room temp., initial pressure 34 atm, 24h; rinsing react. mixt. with pentane into retort; evapn.; addn. of pentane; cooling to -15°C; crystn. overnight; filtration; recrystn. (petroleum ether); elem. anal.;
参考文献
Haeberle, Karl; Draeger, Martin
Zeitschrift fuer Naturforschung, B: Chemical Sciences, 1987 , vol. 42, # 3 p. 323 - 329
in neat (no solvent) High Pressure; pressure react. of dry HCl and Ph6Ge2 in autoclave (molar ratio HCl/Ph6Ge2 = 15.0), room temp., initial pressure 43 atm, 4h; rinsing react. mixt. with pentane into retort; evapn.; addn. of pentane; cooling to -15°C; crystn. overnight; filtration; recrystn. (petroleum ether); elem. anal.;
参考文献
Haeberle, Karl; Draeger, Martin
Zeitschrift fuer Naturforschung, B: Chemical Sciences, 1987 , vol. 42, # 3 p. 323 - 329
