反应条件
Mg; HCl in diethyl ether; toluene according to J. Chem. Soc. (1962) 3509; under dry O2-free Ar using Schlenk techniques; soln. of PhBr (348.00 mmol) in ether added dropwise to suspn. of Mg (417.00 mmol) in ether; refluxed (1 h); soln. of GeCl4 (24.80mmol) added; refluxed (4 h); cooled to room temp.; 10percent HCl in toluene added; solid filtered off; washed with hot toluene and H2O; extd. with CHCl3 (40 h);
参考文献
Zaitsev, Kirill V.; Kapranov, Andrey A.; Oprunenko, Yuri F.; Churakov, Andrei V.; Howard, Judith A.K.; Tarasevich, Boris N.; Karlov, Sergey S.; Zaitseva, Galina S.
Journal of Organometallic Chemistry, 2012 , vol. 700, p. 207 - 213
