pentacarbonyliron(0) bombarded with 100 eV electrons, single and double dehydrogenation; Product distribution;

暂无反应条件数据

hydrogen; platinum(IV) oxide in tetrahydrofuran P=1034.3 Torr;

nickel T=310°C; P=102971 Torr; Hydrogenation;

hydrogen T=240°C; P=760.051 Torr; TemperatureReagent/catalyst;

hydrogen

hydrogen; aluminum oxide; molybdenum(IV) disulfide T=400°C; P=51485.6 Torr; 1 h; other catalysts; Product distribution;

sodium hydroxide in isopropyl alcohol T=20°C; Birch-type reduction; 2 h; UV-irradiation;

1: 63 percent / NaOEt / 7 h / Heating 2: 98 percent / KOH / ethanol; H2O / 6 h / Heating 3: 95 percent / 170 °C 4: thionyl chloride / 0.75 h / Heating 5: 85 percent / AlCl3 / CS2 / 3 h / Heating 6: 89 percent / NaBH4 / ethanol; tetrahydrofuran 7: 96 percent / p-toluenesulfonic acid / benzene / Heating 8: 98 percent / NiCl2<dppp>2 / diethyl ether / Heating 9: 99 percent / H2 / PtO2 / tetrahydrofuran / 1034.3 Torr View Scheme

1: 91 percent / sulfuric acid / H2O / 4 h / Heating 2: 84 percent / LiAlH4 / diethyl ether / 1 h / Heating 3: 72 percent / 48percent HBr, H2SO4 / 3 h / Heating 4: 63 percent / NaOEt / 7 h / Heating 5: 98 percent / KOH / ethanol; H2O / 6 h / Heating 6: 95 percent / 170 °C 7: thionyl chloride / 0.75 h / Heating 8: 85 percent / AlCl3 / CS2 / 3 h / Heating 9: 89 percent / NaBH4 / ethanol; tetrahydrofuran 10: 96 percent / p-toluenesulfonic acid / benzene / Heating 11: 98 percent / NiCl2<dppp>2 / diethyl ether / Heating 12: 99 percent / H2 / PtO2 / tetrahydrofuran / 1034.3 Torr View Scheme