(Z)-8-十二烯基乙酸酯合成路线 （共 53 条）
反应条件
pyridine in dichloromethane T=20°C; 12 h; Inert atmosphere; chemoselective reaction;
参考文献
Herbert, Myles B.; Marx, Vanessa M.; Pederson, Richard L.; Grubbs, Robert H.
Angewandte Chemie - International Edition, 2013 , vol. 52, # 1 p. 310 - 314
Angew. Chem., 2012 , vol. 125, # 1 p. 328 - 332,5
反应条件
quinoline; hydrogen; Pd-BaSO4 in methanol
参考文献
Ranganathan, S.; Maniktala, Vibha; Kumar, Raaj; Singh, G. P.
Indian Journal of Chemistry, Section B: Organic Chemistry Including Medicinal Chemistry, 1984 , vol. 23, # 12 p. 1197 - 1207
反应条件
C32H41N3O4Ru in tetrahydrofuran T=20°C; 4 h; Inert atmosphereGlovebox; chemoselective reaction;
参考文献
Herbert, Myles B.; Marx, Vanessa M.; Pederson, Richard L.; Grubbs, Robert H.
Angewandte Chemie - International Edition, 2013 , vol. 52, # 1 p. 310 - 314
Angew. Chem., 2012 , vol. 125, # 1 p. 328 - 332,5
反应条件
in DMF (N,N-dimethyl-formamide) T=55 - 110°C; 5 h;
参考文献
3M Innovative Properties Company
Patent: US6838576 B1, 2005 ;
Location in patent: Page column 10-11 ;
反应条件
acetic acid T=60°C; 6 h;
参考文献
Chan, T. H.; Koumaglo, K.
Journal of Organometallic Chemistry, 1985 , vol. 285, p. 109 - 120
反应条件
1: H2 / Lindlar catalyst / methanol 2: Py / benzene View Scheme
参考文献
Odinokov, V. N.; Ishmuratov, G. Yu.; Balezina, G. G.; Tolstikov, G. A.
Chemistry of Natural Compounds, 1985 , vol. 21, # 3 p. 372 - 374
Khimiya Prirodnykh Soedinenii, 1985 , vol. 21, # 3 p. 398 - 400
反应条件
1: 89 percent / NH2 / tetrahydrofuran; dimethylsulfoxide 2: 1) 9-BBN, 2) H2O2, AcONa 3: 85 percent / H2 / Ni-P2 4: 89 percent / pyridine View Scheme
参考文献
Odinokov, V. N.; Ishmuratov, G. Yu.; Balezina, G. G.; Tolstikov, G. A.
Chemistry of Natural Compounds, 1985 , vol. 21, # 3 p. 372 - 374
Khimiya Prirodnykh Soedinenii, 1985 , vol. 21, # 3 p. 398 - 400
反应条件
1: KO-tBu, n-BuLi / hexane; diethyl ether / -78 deg C up to RT for 17 h 2: 1.) ICl; 2.) aq. KF / 1.) CCl4, 15 min; 2.) DMSO, RT, 4 h 3: 88 percent / (Ph3P)4Pd / tetrahydrofuran / Ambient temperature 4: 77 percent / HOAc / 6 h / 60 °C View Scheme
参考文献
Chan, T. H.; Koumaglo, K.
Journal of Organometallic Chemistry, 1985 , vol. 285, p. 109 - 120
反应条件
1: 88 percent / (Ph3P)4Pd / tetrahydrofuran / Ambient temperature 2: 77 percent / HOAc / 6 h / 60 °C View Scheme
参考文献
Chan, T. H.; Koumaglo, K.
Journal of Organometallic Chemistry, 1985 , vol. 285, p. 109 - 120
反应条件
1: 1.) ICl; 2.) aq. KF / 1.) CCl4, 15 min; 2.) DMSO, RT, 4 h 2: 88 percent / (Ph3P)4Pd / tetrahydrofuran / Ambient temperature 3: 77 percent / HOAc / 6 h / 60 °C View Scheme
参考文献
Chan, T. H.; Koumaglo, K.
Journal of Organometallic Chemistry, 1985 , vol. 285, p. 109 - 120
