1-环状己烯三氟甲烷磺酸合成路线 （共 56 条）
反应条件
1: n-hexyl lithium With zinc(II) chloride in tetrahydrofuran T=20°C; 2: carbon monoxide; cyclohex-1-en-1-yl trifluoromethanesulfonate With magnesium bromide; nickel dichloride in tetrahydrofuran; dimethyl sulfoxide T=80°C; Negishi coupling; P=760.051 Torr; 0.333333 h; Further stages.;
参考文献
Wang, Qiaoling; Chen, Chuo
Tetrahedron Letters, 2008 , vol. 49, # 18 p. 2916 - 2921
反应条件
pyridine; 1,1'-bis-(diphenylphosphino)ferrocene; palladium diacetate T=150°C; 0.333333 h; microwave irradiation;
参考文献
Lesma, Giordano; Sacchetti, Alessandro; Silvani, Alessandra
Synthesis, 2006 , # 4 p. 594 - 596
反应条件
Bromoeosine in tetrahydrofuran T=20°C; IrradiationFlow reactor;
参考文献
Cantillo, David; De Frutos, Oscar; Rincon, Juan A; Mateos, Carlos; Kappe, C. Oliver
Organic Letters, 2014 , vol. 16, # 3 p. 896 - 899
反应条件
[RuIII(2,4-pentanedionato)3]; 1,10-phenanthroline; ethylmagnesium bromide; lithium bromide in tetrahydrofuran T=60°C; 24 h; Inert atmosphere;
参考文献
Shirakawa, Eiji; Imazaki, Yusuke; Hayashi, Tamio
Chemical Communications, 2009 , # 34 p. 5088 - 5090
反应条件
tetraethylammonium bromide; triethylamine T=135°C; 360 h; Product distributionMechanism;
参考文献
Chemische Berichte, , vol. 117, # 9 p. 2815 - 2824
反应条件
1-methyl-pyrrolidin-2-one; iron (III) acetylacetonate in tetrahydrofuran T=-30°C;
参考文献
Scheiper, Bodo; Bonnekessel, Melanie; Krause, Helga; Fuerstner, Alois
Journal of Organic Chemistry, 2004 , vol. 69, # 11 p. 3943 - 3949
反应条件
1: With sodium t-butanolate; tris(dibenzylideneacetone)dipalladium (0); bis[2-(diphenylphosphino)phenyl] ether in 1,4-dioxane T=70°C; 24 h; 2: With hydrogenchloride in tetrahydrofuran; methanol T=20°C; 16 h; Further stages.;
参考文献
Takemiya, Akihiro; Hartwig, John F.
Journal of the American Chemical Society, 2006 , vol. 128, # 46 p. 14800 - 14801
反应条件
triphenylphosphine; [palladium(II)(bis(triphenylphosphanyl))dichloride] in toluene mixt. in toluene stirred at 50°C for 3 h; treated (H2O) at room temp.; extd. (benzene); washed with brine; dried (MgSO4); purified by chromy. on silica gel or by distn. (vac.);
参考文献
Takagi, Jun; Takahashi, Kou; Ishiyama, Tatsuo; Miyaura, Norio
Journal of the American Chemical Society, 2002 , vol. 124, # 27 p. 8001 - 8006
反应条件
triethylamine; (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; triphenyl-arsane in 1,4-dioxane T=80°C; Borylation; 16 h; Title compound not separated from byproducts;
参考文献
Murata, Miki; Oyama, Takashi; Watanabe, Shinji; Masuda, Yuzuru
Synthesis, 2000 , # 6 p. 778 - 780
反应条件
triethylamine; magnesium iodide in cyclohexane T=120°C; 60 h;
参考文献
Garcia Martinez, A.; Martinez Alvarez, R.; Garcia Fraile, A.; Subramanian, L. R.; Hanack, Michael
Synthesis, 1986 , # 3 p. 222 - 224
