1-环状己烯三氟甲烷磺酸合成路线 （共 56 条）
反应条件
potassium fluoride; tris-(dibenzylideneacetone)dipalladium(0) in dimethyl sulfoxide T=55°C; 12 h;
参考文献
Liao, Longyan; Jana, Ranjan; Urkalan, Kaveri Balan; Sigman, Matthew S.
Journal of the American Chemical Society, 2011 , vol. 133, # 15 p. 5784 - 5787
反应条件
1: bromo-(o-methylphenyl)-magnesium With zinc dibromide in tetrahydrofuran T=20°C; 2: carbon monoxide; cyclohex-1-en-1-yl trifluoromethanesulfonate With magnesium bromide; nickel dichloride in tetrahydrofuran; dimethyl sulfoxide T=80°C; Negishi coupling; P=760.051 Torr; 0.333333 h; Further stages.;
参考文献
Wang, Qiaoling; Chen, Chuo
Tetrahedron Letters, 2008 , vol. 49, # 18 p. 2916 - 2921
反应条件
2-(dicyclohexylphosphino)-2',4',6'-tri-i-propyl-1,1’-biphenyl; tris(dibenzylideneacetone)dipalladium (0) in tetrahydrofuran 4 h; Heating;
参考文献
Cooper, Thea; Novak, Andrew; Humphreys, Luke D.; Walker, Matthew D.; Woodward, Simon
Advanced Synthesis and Catalysis, 2006 , vol. 348, # 6 p. 686 - 690
反应条件
tris-(dibenzylideneacetone)dipalladium(0); 2-(dicyclohexylphosphino)-2',4',6'-tri-i-propyl-1,1’-biphenyl in tetrahydrofuran T=90°C; 4 h; Inert atmosphere;
参考文献
Vinogradov, Andrej; Woodward, Simon; Rageot, Denise; Pfaltz, Andreas
Organic Syntheses, 2010 , vol. 87, p. 104 - 114
参考文献
Hosoya, Takamitsu; Sumi, Kengo; Doi, Hisashi; Wakao, Masahiro; Suzuki, Masaaki
Organic and Biomolecular Chemistry, 2006 , vol. 4, # 3 p. 410 - 415
反应条件
aluminium trichloride 0.0833333 h; Ambient temperature; Yield given. Yields of byproduct given;
参考文献
Martinez, A. Garcia; Alvarez, R. Martinez; Fraile, A. Garcia; Hanack, Michael; Subramanian, L. R.
Chemische Berichte, 1987 , vol. 120, p. 1255 - 1256
反应条件
1: propynoic acid methyl ester With n-butyllithium; diisopropylamine in tetrahydrofuran; hexane T=-78°C; 2: With zinc dibromide in tetrahydrofuran; hexane T=-78 - 0°C; 3: cyclohex-1-en-1-yl trifluoromethanesulfonate With tetrakis(triphenylphosphine) palladium(0) in tetrahydrofuran; hexane T=23°C;
参考文献
Negishi, Ei-Ichi; Qian, Mingxing; Zeng, Fanxing; Anastasia, Luigi; Babinski, David
Organic Letters, 2003 , vol. 5, # 10 p. 1597 - 1600
反应条件
hydrogen; Raney-Ni W-2 in ethanol P=760 Torr; 48 h; Ambient temperature;
参考文献
Subramanian, L. R.; Martinez, A. Garcia; Fernandez A. Herrera; Alvarez, R. Martinez
Synthesis, 1984 , # 6 p. 481 - 485
反应条件
pyridine; C48H68P2; hydrogen; palladium diacetate in diethylene glycol dimethyl ether; N,N-dimethyl-formamide T=80°C; P=15001.5 Torr; 16 h;
参考文献
Neumann, Helfried; Sergeev, Alexey; Beller, Matthias
Angewandte Chemie - International Edition, 2008 , vol. 47, # 26 p. 4887 - 4891
反应条件
pyridine; hydrogen; palladium diacetate; di-(1-adamantyl)-n-butylphosphine in N,N-dimethyl-formamide T=80°C; P=15001.5 Torr; 16 h;
参考文献
Angewandte Chemie - International Edition, , vol. 47, # 26 p. 4887 - 4891
