2,6,6-三甲基环己-2-烯-1-羧酸甲酯合成路线 （共 22 条）
反应条件
potassium carbonate in acetone T=20°C; 5 h;
参考文献
Xiong, Yi; Wang, Kuiwu; Pan, Yuanjiang; Sun, Hongxiang; Tu, Jue
Bioorganic and Medicinal Chemistry Letters, 2006 , vol. 16, # 4 p. 786 - 789
反应条件
methanol; epoxysulfonyl fluoride in diethyl ether; ClSO2F (sulfuryl chloride fluoride) T=-120°C;
参考文献
Gavrilyuk, O. A.; Korchagina, D. V.; Bagryanskaya, I. Yu.; Gatilov, Yu. V.; Kron, A. A.; Barkhash, V. A.
Journal of Organic Chemistry USSR (English Translation), 1987 , vol. 23, # 10 p. 1877 - 1890
Zhurnal Organicheskoi Khimii, 1987 , vol. 23, # 10 p. 2124 - 2140
反应条件
4 A molecular sieve; TiF4 in acetonitrile T=0°C;
参考文献
Anastasia, Luigi; Giannini, Elios; Zanoni, Giuseppe; Vidari, Giovanni
Tetrahedron Letters, 2005 , vol. 46, # 35 p. 5803 - 5806
反应条件
potassium carbonate in acetone 24 h; Ambient temperature;
参考文献
Kadas, Istvan; Arvai, Geza; Horyath, Gabriella
Organic Preparations and Procedures International, 1998 , vol. 30, # 1 p. 79 - 85
反应条件
1: 100 percent / NaH 2: 80 percent / nickel(II) bisacetylacetonate 3: 90 percent / stannic chloride / CH2Cl2 / 0 °C 4: stannic chloride / CH2Cl2 View Scheme
参考文献
Armstrong, Rosemary J.; Weiler, Larry
Canadian Journal of Chemistry, 1983 , vol. 61, p. 2530 - 2539
反应条件
2: 100 percent / NaH 3: 80 percent / nickel(II) bisacetylacetonate 4: 90 percent / stannic chloride / CH2Cl2 / 0 °C 5: stannic chloride / CH2Cl2 View Scheme
参考文献
Armstrong, Rosemary J.; Weiler, Larry
Canadian Journal of Chemistry, 1983 , vol. 61, p. 2530 - 2539
反应条件
1: 80 percent / nickel(II) bisacetylacetonate 2: 90 percent / stannic chloride / CH2Cl2 / 0 °C 3: stannic chloride / CH2Cl2 View Scheme
参考文献
Armstrong, Rosemary J.; Weiler, Larry
Canadian Journal of Chemistry, 1983 , vol. 61, p. 2530 - 2539
反应条件
1: 82 percent / phosphate acid / toluene / 2 h / 100 °C 2: 91 percent / K2CO3 / acetone / 5 h / 20 °C View Scheme
参考文献
Nicolaou; Nilewski, Christian; Hale, Christopher R. H.; Ioannidou, Heraklidia A.; Elmarrouni, Abdelatif; Koch, Lizanne G.
Angewandte Chemie - International Edition, 2013 , vol. 52, # 33 p. 8736 - 8741
Angew. Chem., 2013 , vol. 125, # 33 p. 8898 - 8904,7
反应条件
lithium perchlorate; N(Et)4ClO4 in 1,2-dichloro-ethane T=55°C; 0.416667 h; electrolysis; Yield given. Yields of byproduct given. Title compound not separated from byproducts;
参考文献
Uneyama; Isimura; Torii
Bulletin of the Chemical Society of Japan, 1985 , vol. 58, # 6 p. 1859 - 1860
反应条件
2: 100 percent / NaH 3: 80 percent / nickel(II) bisacetylacetonate 4: 90 percent / stannic chloride / CH2Cl2 / 0 °C 5: stannic chloride / CH2Cl2 View Scheme
参考文献
Armstrong, Rosemary J.; Harris, Francis L.; Weiler, Larry
Canadian Journal of Chemistry, 1982 , vol. 60, p. 673 - 675
