9-硼双环[3.3.1]壬烷合成路线 （共 74 条）
反应条件
BACH-EItrade; in 1,4-dioxane hydroboration; Heating;
参考文献
Brown, Herbert C.; Kanth, Josyula V. B.; Zaidlewicz, Marek
Tetrahedron, 1999 , vol. 55, # 19 p. 5991 - 6000
反应条件
acetophenone in tetrahydrofuran Kinetics; 25°C; detected by IR;
参考文献
Brown, Herbert C.; Wang, Kung K.; Chandrasekharan, J.
Journal of the American Chemical Society, 1983 , vol. 105, # 8 p. 2340 - 2343
反应条件
in ethylene glycol dimethyl ether T=20 - 60°C;
参考文献
Weng, Lingkai; Qiao, Lei; Zhou, Jiacheng; Liu, Pingli; Pan, Yongchun
Patent: US2009/291956 A1, 2009 ;
Location in patent: Page/Page column 22 ;
反应条件
BACH-EItrade; in 1,4-dioxane T=20°C; hydroboration; 1 h; Title compound not separated from byproducts;
参考文献
Brown, Herbert C.; Kanth, Josyula V. B.; Zaidlewicz, Marek
Tetrahedron, 1999 , vol. 55, # 19 p. 5991 - 6000
反应条件
in 1,4-dioxane N2-atmosphere; dropwise cyclooctadiene addn. (20°C, stirring), stirring (room temp, 3 h, refluxing , 2 h); crystn. (room temp.), decanting, washing (n-pentane), drying (reduced pressure), recrystn. (THF);
参考文献
Brown, Herbert C.
Organometallics, 1999 , vol. 18, # 7 p. 1310 - 1317
反应条件
Li(t-BuO)3AlH in tetrahydrofuran byproducts: B-alkoxy-9-borabicyclo-[3.3.1]nonane; 0°C, 0.25 h; detected by 11B NMR;
参考文献
Brown, Herbert C.; Kulkarni, Surendra U.
Journal of Organometallic Chemistry, 1981 , vol. 218, # 3 p. 299 - 308
反应条件
Li(CH3O)3AlH in tetrahydrofuran byproducts: B-alkoxy-9-borabicyclo[3.3.1]nonane; 0°C, 0.25 h; detected by 11B NMR;
参考文献
Brown, Herbert C.; Kulkarni, Surendra U.
Journal of Organometallic Chemistry, 1981 , vol. 218, # 3 p. 299 - 308
反应条件
in tetrahydrofuran dropping soln. of BH3*THF in THF to soln. of borane in THF at -78°C, under N2 or Ar; refluxing for 1 h; mechansim discussed;; removal of solvent in vac.; recrystn. from ether; 1. and 2. fraction product mixts., 3. fraction pure 9-borabicyclo(3.3.1)nonane, 4. fraction small amt. of pure (BH2P(tert-butyl)2)2; detn. by NMR;;
参考文献
Noeth, Heinrich; Staude, Siegfried; Thomann, Martina; Paine, Robert T.
Chemische Berichte, 1993 , vol. 126, # 3 p. 611 - 618
反应条件
in not given byproducts: (CH3)2N;
参考文献
Bar-Haim, Galia; Shach, Romem; Kol, Moshe
Chemical Communications, 1997 , # 2 p. 229 - 230
反应条件
in not given byproducts: (CH3)2N;
参考文献
Bar-Haim, Galia; Shach, Romem; Kol, Moshe
Chemical Communications, 1997 , # 2 p. 229 - 230
