5,10,15,20-tetraphenyl-21H,23H-porphine Co(II) in chloroform
T=40°C; 14 h; various saturated bicyclic endoperoxides; investigation of the influence of the ring size and reaction conditions on the CoTPP catalyzed decomposition pathway; Product distributionMechanism;
tris(triphenylphosphine)ruthenium(II) chloride in dichloromethane-d2
T=0°C; 0.25 h; Further byproducts given. Title compound not separated from byproducts;
tetrakis(triphenylphosphine) palladium(0) in dichloromethane
T=28°C; 2 h; var. 1,4-epiperoxides; other reagent, other solvent, other temperature and time; Product distributionMechanism;
