3-甲基-1,3-戊二烯合成路线 (共 10 条)
反应条件
1: 74.3 percent / ethanol 2: 85.8 percent / air; KOH / ethanol / Heating View Scheme
参考文献
Karatsu, Takashi; Itoh, Hajime; Yoshikawa, Nobuko; Kitamura, Akihide; Tokumaru, Katsumi
Bulletin of the Chemical Society of Japan, 1999 , vol. 72, # 8 p. 1837 - 1849
反应条件
W(CO)5(NCCH3) in dichloromethane-d2
T=25°C; 24 h;
参考文献
Adams, Richard D.; Perrin, Joseph L.
Journal of the American Chemical Society, 1999 , vol. 121, # 16 p. 3984 - 3991
反应条件
tri-isobutyl aluminium; Ni(mesal) in pentane
T=25°C; 15 h;
参考文献
Caporusso, Anna Maria; Giacomelly, Giampaolo; Lardicci, Luciano
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1981 , p. 1900 - 1908
反应条件
toluene-4-sulfonic acid
参考文献
Bartlett,P.D. et al.
Journal of the American Chemical Society, 1968 , vol. 90, p. 2049 - 2056
反应条件
manganese(II) 2,4-pentanedionate in pentane
T=25°C; 10 h;
参考文献
Caporusso, Anna Maria; Giacomelly, Giampaolo; Lardicci, Luciano
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1981 , p. 1900 - 1908
反应条件
in pentane
T=25°C; 40 h;
参考文献
Caporusso, Anna Maria; Giacomelly, Giampaolo; Lardicci, Luciano
Journal of the Chemical Society, Perkin Transactions 1: Organic and Bio-Organic Chemistry (1972-1999), 1981 , p. 1900 - 1908
反应条件
hydrogen bromide in water
Dehydration; Heating; Title compound not separated from byproducts;
参考文献
Viktorov; Zubritskii
Russian Journal of Organic Chemistry, 1999 , vol. 35, # 12 p. 1755 - 1765
反应条件
tetrabutyl ammonium fluoride
参考文献
Nativi, Cristina; Taddei, Maurizio; Mann, Andre
Tetrahedron, 1989 , vol. 45, # 4 p. 1131 - 1144
反应条件
(i) K, Et3N, (ii) H2O; Multistep reaction;
参考文献
Yasuda,H. et al.
Bulletin of the Chemical Society of Japan, 1979 , vol. 52, p. 2036 - 2045
反应条件
(i) K, Et3N, (ii) H2O; Multistep reaction;
参考文献
Yasuda,H. et al.
Bulletin of the Chemical Society of Japan, 1979 , vol. 52, p. 2036 - 2045