2,4-双(α,α-二甲基苯甲基)苯酚合成路线 （共 7 条）
反应条件
toluene-4-sulfonic acid
参考文献
Ciba-Geigy Corporation
Patent: US4347180 A1, 1982 ;
Title/Abstract Full Text Show Details
Ciba-Geigy Corporation
Patent: US4275004 A1, 1981 ;
反应条件
[Re2(CO)10] in toluene T=150°C; 24 h; Inert atmosphereSealed tube; regioselective reaction;
参考文献
Kuninobu, Yoichiro; Matsuki, Takashi; Takai, Kazuhiko
Journal of the American Chemical Society, 2009 , vol. 131, # 29 p. 9914 - 9915
反应条件
aluminium phenoxide T=110°C;
参考文献
Kochnev; Oleynik; Ivanchev; Tolstikov
Russian Chemical Bulletin, 2007 , vol. 56, # 6 p. 1125 - 1129
反应条件
aluminium T=135°C; 3 h; Further byproducts given;
参考文献
Kurashev, M. V.; Struchkov, Yu. T.; Veretyakhina, T. G.; Shklover, V. E.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1986 , vol. 35, # 8 p. 1673 - 1676
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1986 , # 8 p. 1843 - 1846
反应条件
aluminium T=135°C; 3 h; dependence of the yield of the alkylation products on temperature, on the concentration of reagent, on the reaction time; Product distribution;
参考文献
Kurashev, M. V.; Struchkov, Yu. T.; Veretyakhina, T. G.; Shklover, V. E.
Bulletin of the Academy of Sciences of the USSR, Division of Chemical Science (English Translation), 1986 , vol. 35, # 8 p. 1673 - 1676
Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1986 , # 8 p. 1843 - 1846
反应条件
1: With SCl2; zinc(II) chloride in hexane
48 h;
2: With dihydrogen peroxide; acetic acid
2 h; Heating;
参考文献
Chandrasekaran; Timosheva, Natalya V.; Holmes, Robert R.
Phosphorus, Sulfur and Silicon and the Related Elements, 2006 , vol. 181, # 7 p. 1493 - 1511
反应条件
disulfur dichloride; titanium tetrachloride in toluene
T=-5 - 20°C; 72.5 h;
参考文献
Marcsekova, Klaudia; Loos, Christian; Rominger, Frank; Doye, Sven
Synlett, 2007 , # 16 p. 2564 - 2568
