反应条件
hydrogen in dichloromethane dry solvents; degassing isonitrile and Mo-compd. dissolved in CH2Cl2, placing under hydrogen (375-400 Torr), stirring at ambient temperature (6 days); removal of solvent, extn. (toluene), filtration, shaking residue (Et2O/Na2CO3), filtration, extn. residue (MeCN), filtration, crystn. by addn. of Et2O, filtration, drying in vac.; (CpMo)2(S2CH2)2 and ((CpMo)2S4C6H12N)CF3SO3 not isolated, detn. (1)H-NMR;
参考文献
Bernatis, Paul; Laurie, J. C. V.; Rakowski DuBoi, M.
Organometallics, 1990 , vol. 9, p. 1607 - 1617
